Synthesis and properties of new PDT- and TPDT-TTP analogues

T. Kaibuki, Y. Misaki, K. Tanaka, K. Takimiya, A. Morikami, T. Otsubo

Research output: Contribution to journalConference articlepeer-review

7 Citations (Scopus)

Abstract

2-(1,3-Diselenol-2-ylidene)-5-(pyran-4-ylidene)- 1,3,4,6-tetrathiapentalene (PDS-TTP), its thiopyran analogue (TPDS-TTP), and their bis(methylthio) derivatives have been prepared. Their first and second oxidation potentials are comparable to those of the corresponding sulfur analogues. The PF6 and AsF6 salt of PDS-TTP displayed metallic conductivity down to 4.2 K, and TCNQ complex was semiconductor with a low activation energy (0.006 eV).

Original languageEnglish
Pages (from-to)1621-1622
Number of pages2
JournalSynthetic Metals
Volume102
Issue number1-3
DOIs
Publication statusPublished - 1999 Jun
Externally publishedYes
EventProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
Duration: 1998 Jul 121998 Jul 18

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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