Synthesis and properties of bitetraselenafulvalene

Masahiko Iyoda, Kenji Hara, C. R. Venkateswara Rao, Yoshiyuki Kuwatani, Kazuo Takimiya, Atsushi Morikami, Aso Yoshio, Tetsuo Otsubo

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Copper(II)- and palladium(II)-catalyzed homo-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities.

Original languageEnglish
Pages (from-to)5729-5730
Number of pages2
JournalTetrahedron Letters
Volume40
Issue number31
DOIs
Publication statusPublished - 1999 Jul 30
Externally publishedYes

Keywords

  • Coupling reactions
  • Electron donors
  • Physical properties
  • X-ray crystal structures

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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