Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure

Zornitza Glavcheva; Hirohito Umezawa; Yoshihiro Mineno; Toru Odani; Shuji Okada; Satoshi Ikeda; Tetsuo Taniuchi; Hachiro Nakanishi

doi:10.1143/JJAP.44.5231

Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure

Zornitza Glavcheva, Hirohito Umezawa, Yoshihiro Mineno, Toru Odani, Shuji Okada, Satoshi Ikeda, Tetsuo Taniuchi, Hachiro Nakanishi

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

DAST, 1-methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridinium p-toluenesulfonate, has been recently reported as an efficient THz-wave generator by difference frequency generation. In this study, two DAST derivatives, i.e., perdeuterated DAST (DAST-d₂₆) and DASC with p-chlorobenzenesulfonate replacing the p-toluenesulfonate of DAST, were investigated as model compounds to analyze the THz-wave intensity variation of DAST as a function of frequency. X-ray crystallographic analyses of DAST-d ₂₆ and DASC were carried out for the first time, and it was found that both compounds gave crystals isomorphous with DAST. Their basic properties were also investigated.

Original language	English
Pages (from-to)	5231-5235
Number of pages	5
Journal	Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume	44
Issue number	7 A
DOIs	https://doi.org/10.1143/JJAP.44.5231
Publication status	Published - 2005 Jul 8
Externally published	Yes

Keywords

DAST
Isomorphism
Organic ionic crystal
Second-order nonlinear optics
THz-wave geranation

ASJC Scopus subject areas

Engineering(all)
Physics and Astronomy(all)

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10.1143/JJAP.44.5231

Cite this

Glavcheva, Z., Umezawa, H., Mineno, Y., Odani, T., Okada, S., Ikeda, S., Taniuchi, T., & Nakanishi, H. (2005). Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure. Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 44(7 A), 5231-5235. https://doi.org/10.1143/JJAP.44.5231

Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure. / Glavcheva, Zornitza; Umezawa, Hirohito; Mineno, Yoshihiro et al.

In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 44, No. 7 A, 08.07.2005, p. 5231-5235.

Research output: Contribution to journal › Article › peer-review

Glavcheva, Z, Umezawa, H, Mineno, Y, Odani, T, Okada, S, Ikeda, S, Taniuchi, T & Nakanishi, H 2005, 'Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure', Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, vol. 44, no. 7 A, pp. 5231-5235. https://doi.org/10.1143/JJAP.44.5231

Glavcheva Z, Umezawa H, Mineno Y, Odani T, Okada S, Ikeda S et al. Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure. Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers. 2005 Jul 8;44(7 A):5231-5235. doi: 10.1143/JJAP.44.5231

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abstract = "DAST, 1-methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridinium p-toluenesulfonate, has been recently reported as an efficient THz-wave generator by difference frequency generation. In this study, two DAST derivatives, i.e., perdeuterated DAST (DAST-d26) and DASC with p-chlorobenzenesulfonate replacing the p-toluenesulfonate of DAST, were investigated as model compounds to analyze the THz-wave intensity variation of DAST as a function of frequency. X-ray crystallographic analyses of DAST-d 26 and DASC were carried out for the first time, and it was found that both compounds gave crystals isomorphous with DAST. Their basic properties were also investigated.",

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AU - Umezawa, Hirohito

AU - Mineno, Yoshihiro

AU - Odani, Toru

AU - Okada, Shuji

AU - Ikeda, Satoshi

AU - Taniuchi, Tetsuo

AU - Nakanishi, Hachiro

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AB - DAST, 1-methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridinium p-toluenesulfonate, has been recently reported as an efficient THz-wave generator by difference frequency generation. In this study, two DAST derivatives, i.e., perdeuterated DAST (DAST-d26) and DASC with p-chlorobenzenesulfonate replacing the p-toluenesulfonate of DAST, were investigated as model compounds to analyze the THz-wave intensity variation of DAST as a function of frequency. X-ray crystallographic analyses of DAST-d 26 and DASC were carried out for the first time, and it was found that both compounds gave crystals isomorphous with DAST. Their basic properties were also investigated.

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Synthesis and properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl} pyridinium p-toluenesulfonate derivatives with isomorphous crystal structure

Abstract

Keywords

ASJC Scopus subject areas

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