Synthesis and photoproperties of edge-functionalized zeolite-templated carbon with bromine or carbazole groups

Haruko Goto, Tomoyuki Tajima, Kazumasa Kobayashi, Yutaka Takaguchi, Khanin Nueangnoraj, Hirotomo Nishihara

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    We succeeded in synthesizing edge-brominated zeolite-templated carbon (ZTC-Br) as the key intermediate of edge-functionalization of ZTC via an electrophilic aromatic substitution reaction using dibromoisocyanuric acid. ZTC-Br was easily converted into carbazole-modified ZTC (ZTC-Cz) using Suzuki-Miyaura coupling. Interestingly, solvent-dependent changes of the fluorescence intensity of ZTC-Cz owing to its swelling-shrinking behavior were observed.

    Original languageEnglish
    Pages (from-to)601-603
    Number of pages3
    JournalChemistry Letters
    Volume45
    Issue number6
    DOIs
    Publication statusPublished - 2016

    Keywords

    • Solvatochromism
    • Suzuki-Miyaura cross coupling
    • Zeolite-templated carbon (ZTC)

    ASJC Scopus subject areas

    • Chemistry(all)

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