Synthesis and photophysical properties of expanded dehydrobenzoannulene macrotricycles

Takashi Takeda, Michael M. Haley

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A sequential Sonogashira cross-coupling/Pd-mediated oxidative homocoupling strategy affords two expanded dehydrobenzoannulene (DBA) structures containing two [14]DBAs fused to an [18]DBA core. Noticeable differences in the absorption and emission spectra are observed in comparison with a structurally related [18]DBA-centered trefoil containing three fused [14]DBAs.

Original languageEnglish
Pages (from-to)298-302
Number of pages5
JournalCanadian Journal of Chemistry
Volume95
Issue number3
DOIs
Publication statusPublished - 2017 Jan 1

Keywords

  • macrocycles
  • optoelectronic properties
  • phenylacetylenes
  • π-electron rich

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

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