Synthesis and photophysical properties of expanded dehydrobenzoannulene macrotricycles

Takashi Takeda; Michael M. Haley

doi:10.1139/cjc-2016-0430

Synthesis and photophysical properties of expanded dehydrobenzoannulene macrotricycles

Takashi Takeda, Michael M. Haley

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A sequential Sonogashira cross-coupling/Pd-mediated oxidative homocoupling strategy affords two expanded dehydrobenzoannulene (DBA) structures containing two [14]DBAs fused to an [18]DBA core. Noticeable differences in the absorption and emission spectra are observed in comparison with a structurally related [18]DBA-centered trefoil containing three fused [14]DBAs.

Original language	English
Pages (from-to)	298-302
Number of pages	5
Journal	Canadian Journal of Chemistry
Volume	95
Issue number	3
DOIs	https://doi.org/10.1139/cjc-2016-0430
Publication status	Published - 2017 Jan 1

Keywords

macrocycles
optoelectronic properties
phenylacetylenes
π-electron rich

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Organic Chemistry

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abstract = "A sequential Sonogashira cross-coupling/Pd-mediated oxidative homocoupling strategy affords two expanded dehydrobenzoannulene (DBA) structures containing two [14]DBAs fused to an [18]DBA core. Noticeable differences in the absorption and emission spectra are observed in comparison with a structurally related [18]DBA-centered trefoil containing three fused [14]DBAs.",

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AU - Haley, Michael M.

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AB - A sequential Sonogashira cross-coupling/Pd-mediated oxidative homocoupling strategy affords two expanded dehydrobenzoannulene (DBA) structures containing two [14]DBAs fused to an [18]DBA core. Noticeable differences in the absorption and emission spectra are observed in comparison with a structurally related [18]DBA-centered trefoil containing three fused [14]DBAs.

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KW - optoelectronic properties

KW - phenylacetylenes

KW - π-electron rich

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Synthesis and photophysical properties of expanded dehydrobenzoannulene macrotricycles

Abstract

Keywords

ASJC Scopus subject areas

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