Synthesis and photophysical properties of expanded dehydrobenzoannulene macrotricycles

Takashi Takeda, Michael M. Haley

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    A sequential Sonogashira cross-coupling/Pd-mediated oxidative homocoupling strategy affords two expanded dehydrobenzoannulene (DBA) structures containing two [14]DBAs fused to an [18]DBA core. Noticeable differences in the absorption and emission spectra are observed in comparison with a structurally related [18]DBA-centered trefoil containing three fused [14]DBAs.

    Original languageEnglish
    Pages (from-to)298-302
    Number of pages5
    JournalCanadian Journal of Chemistry
    Volume95
    Issue number3
    DOIs
    Publication statusPublished - 2017 Jan 1

    Keywords

    • macrocycles
    • optoelectronic properties
    • phenylacetylenes
    • π-electron rich

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)
    • Organic Chemistry

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