Abstract
Pr3+-activated CaSnO3 (CaSnO3:Pr3+) was prepared herein through the amorphous metal complex (AMC) method using a stable water-soluble Sn4+ complex coordinated to lactic acid. The photoluminescence properties of CaSnO3:Pr3+ were found to be significantly sensitive for the small deviation of the Sn/(Ca + Pr) ratio. The emission intensities of CaSnO3:Pr3+ with the Sn/(Ca + Pr) ratios between 1.00 and 1.01 were relatively high, whereas the emission intensity remarkably decreased with the decreasing Sn/(Ca + Pr) ratio from 1.00 to 0.98. The CaSnO3:Pr3+ prepared under the optimum condition through the AMC method showed a high emission intensity under UV irradiation, which was 1.9 times higher than that of CaSnO3:Pr3+ prepared by the conventional solid-state reaction method.
Original language | English |
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Pages (from-to) | 648-653 |
Number of pages | 6 |
Journal | Journal of Solid State Chemistry |
Volume | 277 |
DOIs | |
Publication status | Published - 2019 Sep |
Keywords
- Amorphous metal complex method
- Perovskite
- Phosphor
- Photoluminescence
- Pr-activated CaSnO
- Water-soluble Sn complex
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry