Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2- Cl)RhCp*][PF6](Cp* = η5-C5Me5)

Hiroyuki Matsuzaka, Teruo Kamura, Ko Ariga, Takashi Okubo, Tomohiko Ishii, Masahiro Yamashita, Mitsuru Kondo, Susumu Kitagawa

Research output: Contribution to journalConference articlepeer-review

Abstract

Reaction of [Cp*RhCl2]2 (1) with (LiNH)2C10H6-2,3 gives the mononuclear species Cp*Rh(NH)2C10H6-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ2-(NH)2C10H6- 2,3}(μ2-Cl)RhCp*]PF6 (4; Cp* = η5-C5Me5) upon treatment with 1/AgPF6 in acetone. The molecular structure of 4 has been determined by X-ray crystallography.

ASJC Scopus subject areas

  • Condensed Matter Physics

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Dive into the research topics of 'Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp<sup>*</sup>Rh{μ<sub>2</sub>-(NH)<sub>2</sub>C<sub>10</sub>H<sub>6</sub>-2,3}(μ<sub>2</sub>- Cl)RhCp<sup>*</sup>][PF<sub>6</sub>](Cp<sup>*</sup> = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)'. Together they form a unique fingerprint.

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