Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2- Cl)RhCp*][PF6](Cp* = η5-C5Me5)

Hiroyuki Matsuzaka, Teruo Kamura, Ko Ariga, Takashi Okubo, Tomohiko Ishii, Masahiro Yamashita, Mitsuru Kondo, Susumu Kitagawa

Research output: Contribution to journalConference articlepeer-review

Abstract

Reaction of [Cp*RhCl2]2 (1) with (LiNH)2C10H6-2,3 gives the mononuclear species Cp*Rh(NH)2C10H6-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ2-(NH)2C10H6- 2,3}(μ2-Cl)RhCp*]PF6 (4; Cp* = η5-C5Me5) upon treatment with 1/AgPF6 in acetone. The molecular structure of 4 has been determined by X-ray crystallography.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume342
DOIs
Publication statusPublished - 2000
Externally publishedYes
EventProceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) - Kyoto, Jpn
Duration: 1999 Nov 301999 Dec 2

ASJC Scopus subject areas

  • Condensed Matter Physics

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