Synthesis and magnetic properties of ba2mn2si 2o9: The first example of s=2 spin-dimer with spin-singlet ground state

Zhangzhen He, Myung Hwan Wangbo, Yutaka Ueda, Yasuo Narumi, Koichi Kindo, Tomoyasu Taniyama, Mitsuru Itoh, Wendan Cheng

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Correlation of structure and property: Ba2Mn2Si 2O9 consists of Mn2O8 dimers made up of two basaledge-sharing MnO5 square pyramids. Magnetic measurements show that this material displays a spin-singlet ground state with a large spin gap. The spin-dimer analysis suggests that the origin of the spin gap is likely to arise from a large intra-dimer interaction between the Mn1O5 and Mn 2O5 square pyramids.

Original languageEnglish
Pages (from-to)1530-1535
Number of pages6
JournalChemistry - An Asian Journal
Volume4
Issue number10
DOIs
Publication statusPublished - 2009 Oct 5

Keywords

  • Crystal growth
  • Magnetic properties manganese
  • Silicates
  • Theoretical calculations

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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