Synthesis and facile ring expansion of silylenecyclotetrasilane

Takeaki Iwamoto, Yuichi Furiya, Hideki Kobayashi, Hiroyuki Isobe, Mitsuo Kira

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Silylenecyclotetrasilane 4 synthesized as marginally stable orange crystals undergoes ring expansion to give cyclopentasilene 5 quantitatively with the activation parameters of δH = 24.8 ± 1.0 kcal mol-1 and δS = +6.5 ± 3.2 cal mol-1 K-1. The activation parameters and DFT calculations support that the isomerization of 4 to 5 proceeds through stepwise double 1,2-silyl migrations.

Original languageEnglish
Pages (from-to)1869-1872
Number of pages4
JournalOrganometallics
Volume29
Issue number8
DOIs
Publication statusPublished - 2010 Apr 26

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Synthesis and facile ring expansion of silylenecyclotetrasilane'. Together they form a unique fingerprint.

  • Cite this