Synthesis and dynamic behaviour of 1-(dipropylboryl)cyclohepta-2,4-diene

Ilya D. Gridnev, Mikhail E. Gurskii, Alexey V. Geiderikh, Yurii N. Bubnov

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Two sequential [1,3] boron shifts in 1-(dipropylboryl)cyclohepta-2,4-diene 1 result in a degenerate rearrangement (EA = 98.9±3.3 kJ mol-1, In A = 39.3±1.4, ΔG298 = 118.3±0.3 kJ mol-1); reaction of 1 with acetone affords non-conjugated alcohol 2.

Original languageEnglish
Pages (from-to)185-187
Number of pages3
JournalMendeleev Communications
Volume6
Issue number5
DOIs
Publication statusPublished - 1996
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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