Synthesis and characterization of phthalocyanine-based soluble light-harvesting CIGS complex

Yu Chen; Xiaodong Zhuang; Weian Zhang; Ying Liu; Ying Lin; Aixia Yan; Yasuyuki Araki; Osamu Ito

doi:10.1021/cm0713172

Synthesis and characterization of phthalocyanine-based soluble light-harvesting CIGS complex

Yu Chen, Xiaodong Zhuang, Weian Zhang, Ying Liu, Ying Lin, Aixia Yan, Yasuyuki Araki, Osamu Ito

Division of Organic- and Biomaterials Research

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

An easy and versatile solution-based route for the synthesis of a new phthalocyanine-based light-harvesting material PCIGS [Cu₂(tBu ₄PcGa)(tBu₄PcIn)S₂TPP₂] is described. This material is prepared through a one-pot reaction of tBu ₄PcM-Cl (M = Ga, In), CuI, and [(CH₃)₃Si] ₂S in the presence of triphenyl phosphine. In contrast to the dilute solution, the linear absorption coefficient of PCIGS complex in the solid state (α₀ = 145.35 cm^-1) is about 150 times greater than the dilute solution (α₀ = 0.95 cm^-1) under the conditions of the study. The molecular structure of this material is proposed on the basis of the extended X-ray absorption fine structure spectroscopy.

Original language	English
Pages (from-to)	5256-5261
Number of pages	6
Journal	Chemistry of Materials
Volume	19
Issue number	22
DOIs	https://doi.org/10.1021/cm0713172
Publication status	Published - 2007 Oct 30

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/cm0713172

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title = "Synthesis and characterization of phthalocyanine-based soluble light-harvesting CIGS complex",

abstract = "An easy and versatile solution-based route for the synthesis of a new phthalocyanine-based light-harvesting material PCIGS [Cu2(tBu 4PcGa)(tBu4PcIn)S2TPP2] is described. This material is prepared through a one-pot reaction of tBu 4PcM-Cl (M = Ga, In), CuI, and [(CH3)3Si] 2S in the presence of triphenyl phosphine. In contrast to the dilute solution, the linear absorption coefficient of PCIGS complex in the solid state (α0 = 145.35 cm-1) is about 150 times greater than the dilute solution (α0 = 0.95 cm-1) under the conditions of the study. The molecular structure of this material is proposed on the basis of the extended X-ray absorption fine structure spectroscopy.",

author = "Yu Chen and Xiaodong Zhuang and Weian Zhang and Ying Liu and Ying Lin and Aixia Yan and Yasuyuki Araki and Osamu Ito",

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T1 - Synthesis and characterization of phthalocyanine-based soluble light-harvesting CIGS complex

AU - Chen, Yu

AU - Zhuang, Xiaodong

AU - Zhang, Weian

AU - Liu, Ying

AU - Lin, Ying

AU - Yan, Aixia

AU - Araki, Yasuyuki

AU - Ito, Osamu

PY - 2007/10/30

Y1 - 2007/10/30

N2 - An easy and versatile solution-based route for the synthesis of a new phthalocyanine-based light-harvesting material PCIGS [Cu2(tBu 4PcGa)(tBu4PcIn)S2TPP2] is described. This material is prepared through a one-pot reaction of tBu 4PcM-Cl (M = Ga, In), CuI, and [(CH3)3Si] 2S in the presence of triphenyl phosphine. In contrast to the dilute solution, the linear absorption coefficient of PCIGS complex in the solid state (α0 = 145.35 cm-1) is about 150 times greater than the dilute solution (α0 = 0.95 cm-1) under the conditions of the study. The molecular structure of this material is proposed on the basis of the extended X-ray absorption fine structure spectroscopy.

AB - An easy and versatile solution-based route for the synthesis of a new phthalocyanine-based light-harvesting material PCIGS [Cu2(tBu 4PcGa)(tBu4PcIn)S2TPP2] is described. This material is prepared through a one-pot reaction of tBu 4PcM-Cl (M = Ga, In), CuI, and [(CH3)3Si] 2S in the presence of triphenyl phosphine. In contrast to the dilute solution, the linear absorption coefficient of PCIGS complex in the solid state (α0 = 145.35 cm-1) is about 150 times greater than the dilute solution (α0 = 0.95 cm-1) under the conditions of the study. The molecular structure of this material is proposed on the basis of the extended X-ray absorption fine structure spectroscopy.

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