Synthesis and characterization of Ag5-xPb2O6-δ

Kouta Iwasaki; Hisanori Yamane; Shunichi Kubota; Junichi Takahashi; Yuzuru Miyazaki; Tsuyoshi Kajitani; Kensuke Nakajima; Tsutomu Yamashita; Masahiko Shimada

doi:10.1016/S0921-4534(02)01223-6

Synthesis and characterization of Ag_5-xPb₂O_6-δ

Kouta Iwasaki, Hisanori Yamane, Shunichi Kubota, Junichi Takahashi, Yuzuru Miyazaki, Tsuyoshi Kajitani, Kensuke Nakajima, Tsutomu Yamashita, Masahiko Shimada

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Ag_4.64Pb₂O_5.87, a silver and oxygen defects phase of Ag₅Pb₂O₆, was prepared by solid state reaction of Ag₂O and PbO at 773 K in O₂ of 1.2 MPa. The crystal structure was analyzed by the Rietveld method using X-ray powder diffraction data. The c-axis length changed from 6.427 to 6.433 Å in 0.25<x<0.50 while the a-axis length was almost constant around 5.942 Å. Ag_4.64Pb₂O_5.87 exhibited metallic temperature dependence of electrical resistivity in the temperature range of 10-400 K. The value of the resistivity was in the order of 10^-4 Ωcm. The Seebeck coefficient ranged from -4 to 0 μV/K below 300 K, which revealed that the main conductive carrier is electron. Diamagnetism of the order of 10^-7 emu/g was measured at 5-350 K.

Original language	English
Pages (from-to)	263-268
Number of pages	6
Journal	Physica C: Superconductivity and its applications
Volume	382
Issue number	2-3
DOIs	https://doi.org/10.1016/S0921-4534(02)01223-6
Publication status	Published - 2002 Nov 1

Keywords

AgPbO
Defect structure
Electrical resistivity
Magnetic susceptibility
Seebeck coefficient
Silver lead oxide

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Energy Engineering and Power Technology
Electrical and Electronic Engineering

Access to Document

10.1016/S0921-4534(02)01223-6

Cite this

@article{08ca908004564ebba3404aac6ab89ed8,

title = "Synthesis and characterization of Ag5-xPb2O6-δ",

abstract = "Ag4.64Pb2O5.87, a silver and oxygen defects phase of Ag5Pb2O6, was prepared by solid state reaction of Ag2O and PbO at 773 K in O2 of 1.2 MPa. The crystal structure was analyzed by the Rietveld method using X-ray powder diffraction data. The c-axis length changed from 6.427 to 6.433 {\AA} in 0.254.64Pb2O5.87 exhibited metallic temperature dependence of electrical resistivity in the temperature range of 10-400 K. The value of the resistivity was in the order of 10-4 Ωcm. The Seebeck coefficient ranged from -4 to 0 μV/K below 300 K, which revealed that the main conductive carrier is electron. Diamagnetism of the order of 10-7 emu/g was measured at 5-350 K.",

keywords = "AgPbO, Defect structure, Electrical resistivity, Magnetic susceptibility, Seebeck coefficient, Silver lead oxide",

author = "Kouta Iwasaki and Hisanori Yamane and Shunichi Kubota and Junichi Takahashi and Yuzuru Miyazaki and Tsuyoshi Kajitani and Kensuke Nakajima and Tsutomu Yamashita and Masahiko Shimada",

note = "Funding Information: This work was supported in part by METI, Japan, under the Synergy Ceramics Project.",

year = "2002",

month = nov,

day = "1",

doi = "10.1016/S0921-4534(02)01223-6",

language = "English",

volume = "382",

pages = "263--268",

journal = "Physica C: Superconductivity and its Applications",

issn = "0921-4534",

publisher = "Elsevier",

number = "2-3",

}

TY - JOUR

T1 - Synthesis and characterization of Ag5-xPb2O6-δ

AU - Iwasaki, Kouta

AU - Yamane, Hisanori

AU - Kubota, Shunichi

AU - Takahashi, Junichi

AU - Miyazaki, Yuzuru

AU - Kajitani, Tsuyoshi

AU - Nakajima, Kensuke

AU - Yamashita, Tsutomu

AU - Shimada, Masahiko

N1 - Funding Information: This work was supported in part by METI, Japan, under the Synergy Ceramics Project.

PY - 2002/11/1

Y1 - 2002/11/1

N2 - Ag4.64Pb2O5.87, a silver and oxygen defects phase of Ag5Pb2O6, was prepared by solid state reaction of Ag2O and PbO at 773 K in O2 of 1.2 MPa. The crystal structure was analyzed by the Rietveld method using X-ray powder diffraction data. The c-axis length changed from 6.427 to 6.433 Å in 0.254.64Pb2O5.87 exhibited metallic temperature dependence of electrical resistivity in the temperature range of 10-400 K. The value of the resistivity was in the order of 10-4 Ωcm. The Seebeck coefficient ranged from -4 to 0 μV/K below 300 K, which revealed that the main conductive carrier is electron. Diamagnetism of the order of 10-7 emu/g was measured at 5-350 K.

AB - Ag4.64Pb2O5.87, a silver and oxygen defects phase of Ag5Pb2O6, was prepared by solid state reaction of Ag2O and PbO at 773 K in O2 of 1.2 MPa. The crystal structure was analyzed by the Rietveld method using X-ray powder diffraction data. The c-axis length changed from 6.427 to 6.433 Å in 0.254.64Pb2O5.87 exhibited metallic temperature dependence of electrical resistivity in the temperature range of 10-400 K. The value of the resistivity was in the order of 10-4 Ωcm. The Seebeck coefficient ranged from -4 to 0 μV/K below 300 K, which revealed that the main conductive carrier is electron. Diamagnetism of the order of 10-7 emu/g was measured at 5-350 K.

KW - AgPbO

KW - Defect structure

KW - Electrical resistivity

KW - Magnetic susceptibility

KW - Seebeck coefficient

KW - Silver lead oxide

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U2 - 10.1016/S0921-4534(02)01223-6

DO - 10.1016/S0921-4534(02)01223-6

M3 - Article

AN - SCOPUS:0036838631

VL - 382

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EP - 268

JO - Physica C: Superconductivity and its Applications

JF - Physica C: Superconductivity and its Applications

SN - 0921-4534

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