Syntheses of GM4 and GM3 Intermediates via Alkylation and Subsequent Intramolecular Glycosidation of 2-Alkoxy-2-phenylthioacetate

Takashi Takahashi, Hirokazu Tsukamoto, Haruo Yamada

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

(Matrix presented) We developed a new method for α-glycoside formation of sialyl conjugates based on alkylation and subsequent intramolecular glycosidation of 2-alkoxy-2-phenylthioacetate. By this method we succeeded in the syntheses of GM4 and GM3 intermediates.

Original languageEnglish
Pages (from-to)1885-1887
Number of pages3
JournalOrganic letters
Volume1
Issue number12
DOIs
Publication statusPublished - 1999 Dec 16

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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