Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3

T. Manabe; T. Kawashima; T. Ishii; H. Matsuzaka; Masahiro Yamashita; K. Marumoto; H. Tanaka; S. Kuroda; H. Kitagawa; T. Mitani; H. Okamoto

doi:10.1016/S0379-6779(00)00449-5

Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni_1-xPd_x(chxn)₂Cl₃

T. Manabe, T. Kawashima, T. Ishii, H. Matsuzaka, Masahiro Yamashita, K. Marumoto, H. Tanaka, S. Kuroda, H. Kitagawa, T. Mitani, H. Okamoto

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

A series of single crystals of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni_1-xPd_x(chxn)₂Cl₃ (chxn = 1R,2R-diaminocyclohexane) have been obtained by electrochemical oxidation methods. In order to investigate the competition between the electron correlation in the Ni(III) states and the electron-phonon interaction in the Pd(II)-Pd(IV) mixed-valence states in the Ni-Pd mixed-metal compounds, the infrared spectra, resonance Raman spectra, X-ray photoelectron spectra and Auger spectra have been measured. These results show that the Pd(II)-Pd(IV) mixed-valence states are influenced by Ni(III) and gradually approaching to the Pd(III) states with the increase of the Ni(III) components as observed in Br-bridged complexes, Ni_1-xPd_x(chxn)₂Br₃.

Original language	English
Pages (from-to)	415-418
Number of pages	4
Journal	Synthetic Metals
Volume	116
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(00)00449-5
Publication status	Published - 2001 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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Manabe, T., Kawashima, T., Ishii, T., Matsuzaka, H., Yamashita, M., Marumoto, K., Tanaka, H., Kuroda, S., Kitagawa, H., Mitani, T., & Okamoto, H. (2001). Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni_1-xPd_x(chxn)₂Cl₃. Synthetic Metals, 116(1-3), 415-418. https://doi.org/10.1016/S0379-6779(00)00449-5

Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni_1-xPd_x(chxn)₂Cl₃. / Manabe, T.; Kawashima, T.; Ishii, T.; Matsuzaka, H.; Yamashita, Masahiro; Marumoto, K.; Tanaka, H.; Kuroda, S.; Kitagawa, H.; Mitani, T.; Okamoto, H.

In: Synthetic Metals, Vol. 116, No. 1-3, 01.01.2001, p. 415-418.

Research output: Contribution to journal › Article

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abstract = "A series of single crystals of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3 (chxn = 1R,2R-diaminocyclohexane) have been obtained by electrochemical oxidation methods. In order to investigate the competition between the electron correlation in the Ni(III) states and the electron-phonon interaction in the Pd(II)-Pd(IV) mixed-valence states in the Ni-Pd mixed-metal compounds, the infrared spectra, resonance Raman spectra, X-ray photoelectron spectra and Auger spectra have been measured. These results show that the Pd(II)-Pd(IV) mixed-valence states are influenced by Ni(III) and gradually approaching to the Pd(III) states with the increase of the Ni(III) components as observed in Br-bridged complexes, Ni1-xPdx(chxn)2Br3.",

author = "T. Manabe and T. Kawashima and T. Ishii and H. Matsuzaka and Masahiro Yamashita and K. Marumoto and H. Tanaka and S. Kuroda and H. Kitagawa and T. Mitani and H. Okamoto",

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AU - Kawashima, T.

AU - Ishii, T.

AU - Matsuzaka, H.

AU - Yamashita, Masahiro

AU - Marumoto, K.

AU - Tanaka, H.

AU - Kuroda, S.

AU - Kitagawa, H.

AU - Mitani, T.

AU - Okamoto, H.

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AB - A series of single crystals of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3 (chxn = 1R,2R-diaminocyclohexane) have been obtained by electrochemical oxidation methods. In order to investigate the competition between the electron correlation in the Ni(III) states and the electron-phonon interaction in the Pd(II)-Pd(IV) mixed-valence states in the Ni-Pd mixed-metal compounds, the infrared spectra, resonance Raman spectra, X-ray photoelectron spectra and Auger spectra have been measured. These results show that the Pd(II)-Pd(IV) mixed-valence states are influenced by Ni(III) and gradually approaching to the Pd(III) states with the increase of the Ni(III) components as observed in Br-bridged complexes, Ni1-xPdx(chxn)2Br3.

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