Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3

T. Manabe, T. Kawashima, T. Ishii, H. Matsuzaka, Masahiro Yamashita, K. Marumoto, H. Tanaka, S. Kuroda, H. Kitagawa, T. Mitani, H. Okamoto

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Abstract

A series of single crystals of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3 (chxn = 1R,2R-diaminocyclohexane) have been obtained by electrochemical oxidation methods. In order to investigate the competition between the electron correlation in the Ni(III) states and the electron-phonon interaction in the Pd(II)-Pd(IV) mixed-valence states in the Ni-Pd mixed-metal compounds, the infrared spectra, resonance Raman spectra, X-ray photoelectron spectra and Auger spectra have been measured. These results show that the Pd(II)-Pd(IV) mixed-valence states are influenced by Ni(III) and gradually approaching to the Pd(III) states with the increase of the Ni(III) components as observed in Br-bridged complexes, Ni1-xPdx(chxn)2Br3.

Original languageEnglish
Pages (from-to)415-418
Number of pages4
JournalSynthetic Metals
Volume116
Issue number1-3
DOIs
Publication statusPublished - 2001 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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    Manabe, T., Kawashima, T., Ishii, T., Matsuzaka, H., Yamashita, M., Marumoto, K., Tanaka, H., Kuroda, S., Kitagawa, H., Mitani, T., & Okamoto, H. (2001). Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3. Synthetic Metals, 116(1-3), 415-418. https://doi.org/10.1016/S0379-6779(00)00449-5