Symmetry-Resolved Vibrational Spectroscopy for the C [Formula presented] Renner-Teller Pair States in [Formula presented]

H. Yoshida; K. Nobusada; K. Okada; S. Tanimoto; N. Saito; A. De Fanis; K. Ueda

doi:10.1103/PhysRevLett.88.083001

Symmetry-Resolved Vibrational Spectroscopy for the C [Formula presented] Renner-Teller Pair States in [Formula presented]

H. Yoshida, K. Nobusada, K. Okada, S. Tanimoto, N. Saito, A. De Fanis, K. Ueda

Research output: Contribution to journal › Article › peer-review

Abstract

Symmetry-resolved excitation spectra have been measured for the Renner-Teller pair states [Formula presented] and [Formula presented] split from the core-excited C [Formula presented] state in [Formula presented]. A vibrational progression with the spacings of [Formula presented] is found in both the [Formula presented] and [Formula presented] spectra at different energies and assigned to the symmetric stretching mode caused in the [Formula presented] linear state, with the help of ab initio calculations. Appearance of the vibrations in the [Formula presented] spectrum is interpreted as due to nonadiabatic coupling between the [Formula presented] and [Formula presented] states via the bending motion.

Original language	English
Pages (from-to)	4
Number of pages	1
Journal	Physical review letters
Volume	88
Issue number	8
DOIs	https://doi.org/10.1103/PhysRevLett.88.083001
Publication status	Published - 2002
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1103/PhysRevLett.88.083001

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title = "Symmetry-Resolved Vibrational Spectroscopy for the C [Formula presented] Renner-Teller Pair States in [Formula presented]",

abstract = "Symmetry-resolved excitation spectra have been measured for the Renner-Teller pair states [Formula presented] and [Formula presented] split from the core-excited C [Formula presented] state in [Formula presented]. A vibrational progression with the spacings of [Formula presented] is found in both the [Formula presented] and [Formula presented] spectra at different energies and assigned to the symmetric stretching mode caused in the [Formula presented] linear state, with the help of ab initio calculations. Appearance of the vibrations in the [Formula presented] spectrum is interpreted as due to nonadiabatic coupling between the [Formula presented] and [Formula presented] states via the bending motion.",

author = "H. Yoshida and K. Nobusada and K. Okada and S. Tanimoto and N. Saito and {De Fanis}, A. and K. Ueda",

year = "2002",

doi = "10.1103/PhysRevLett.88.083001",

language = "English",

volume = "88",

pages = "4",

journal = "Physical Review Letters",

issn = "0031-9007",

publisher = "American Physical Society",

number = "8",

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T1 - Symmetry-Resolved Vibrational Spectroscopy for the C [Formula presented] Renner-Teller Pair States in [Formula presented]

AU - Yoshida, H.

AU - Nobusada, K.

AU - Okada, K.

AU - Tanimoto, S.

AU - Saito, N.

AU - De Fanis, A.

AU - Ueda, K.

PY - 2002

Y1 - 2002

N2 - Symmetry-resolved excitation spectra have been measured for the Renner-Teller pair states [Formula presented] and [Formula presented] split from the core-excited C [Formula presented] state in [Formula presented]. A vibrational progression with the spacings of [Formula presented] is found in both the [Formula presented] and [Formula presented] spectra at different energies and assigned to the symmetric stretching mode caused in the [Formula presented] linear state, with the help of ab initio calculations. Appearance of the vibrations in the [Formula presented] spectrum is interpreted as due to nonadiabatic coupling between the [Formula presented] and [Formula presented] states via the bending motion.

AB - Symmetry-resolved excitation spectra have been measured for the Renner-Teller pair states [Formula presented] and [Formula presented] split from the core-excited C [Formula presented] state in [Formula presented]. A vibrational progression with the spacings of [Formula presented] is found in both the [Formula presented] and [Formula presented] spectra at different energies and assigned to the symmetric stretching mode caused in the [Formula presented] linear state, with the help of ab initio calculations. Appearance of the vibrations in the [Formula presented] spectrum is interpreted as due to nonadiabatic coupling between the [Formula presented] and [Formula presented] states via the bending motion.

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DO - 10.1103/PhysRevLett.88.083001

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JF - Physical Review Letters

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Symmetry-Resolved Vibrational Spectroscopy for the C [Formula presented] Renner-Teller Pair States in [Formula presented]

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