Symmetry-resolved absorption spectra of vibrationally excited CO2 molecules

T. Tanaka; C. Makochekanwa; H. Tanaka; M. Kitajima; M. Hoshino; Y. Tamenori; E. Kukk; X. J. Liu; G. Prümper; K. Ueda

doi:10.1103/PhysRevLett.95.203002

Symmetry-resolved absorption spectra of vibrationally excited CO2 molecules

T. Tanaka, C. Makochekanwa, H. Tanaka, M. Kitajima, M. Hoshino, Y. Tamenori, E. Kukk, X. J. Liu, G. Prümper, K. Ueda

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Symmetry-resolved x-ray absorption spectroscopy has been first carried out on high-temperature molecules. From the angle-resolved ion yield spectra of CO2 both at room temperature and at 430°C, symmetry-resolved absorption profiles of the C 1s-12πu and O 1s-12πu resonances have been extracted for the vibrational ground state molecules and bending-vibration excited ones. The profiles change dramatically between them, and the Renner-Teller effect becomes more evident for the vibrationally excited molecules. The effects of the multimode vibronic coupling are suggested for the O 1s-12πu and O 1s-13sσg resonances.

Original language	English
Article number	203002
Journal	Physical review letters
Volume	95
Issue number	20
DOIs	https://doi.org/10.1103/PhysRevLett.95.203002
Publication status	Published - 2005 Nov 11
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1103/PhysRevLett.95.203002

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title = "Symmetry-resolved absorption spectra of vibrationally excited CO2 molecules",

abstract = "Symmetry-resolved x-ray absorption spectroscopy has been first carried out on high-temperature molecules. From the angle-resolved ion yield spectra of CO2 both at room temperature and at 430°C, symmetry-resolved absorption profiles of the C 1s-12πu and O 1s-12πu resonances have been extracted for the vibrational ground state molecules and bending-vibration excited ones. The profiles change dramatically between them, and the Renner-Teller effect becomes more evident for the vibrationally excited molecules. The effects of the multimode vibronic coupling are suggested for the O 1s-12πu and O 1s-13sσg resonances.",

author = "T. Tanaka and C. Makochekanwa and H. Tanaka and M. Kitajima and M. Hoshino and Y. Tamenori and E. Kukk and Liu, {X. J.} and G. Pr{\"u}mper and K. Ueda",

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T1 - Symmetry-resolved absorption spectra of vibrationally excited CO2 molecules

AU - Tanaka, T.

AU - Makochekanwa, C.

AU - Tanaka, H.

AU - Kitajima, M.

AU - Hoshino, M.

AU - Tamenori, Y.

AU - Kukk, E.

AU - Liu, X. J.

AU - Prümper, G.

AU - Ueda, K.

PY - 2005/11/11

Y1 - 2005/11/11

N2 - Symmetry-resolved x-ray absorption spectroscopy has been first carried out on high-temperature molecules. From the angle-resolved ion yield spectra of CO2 both at room temperature and at 430°C, symmetry-resolved absorption profiles of the C 1s-12πu and O 1s-12πu resonances have been extracted for the vibrational ground state molecules and bending-vibration excited ones. The profiles change dramatically between them, and the Renner-Teller effect becomes more evident for the vibrationally excited molecules. The effects of the multimode vibronic coupling are suggested for the O 1s-12πu and O 1s-13sσg resonances.

AB - Symmetry-resolved x-ray absorption spectroscopy has been first carried out on high-temperature molecules. From the angle-resolved ion yield spectra of CO2 both at room temperature and at 430°C, symmetry-resolved absorption profiles of the C 1s-12πu and O 1s-12πu resonances have been extracted for the vibrational ground state molecules and bending-vibration excited ones. The profiles change dramatically between them, and the Renner-Teller effect becomes more evident for the vibrationally excited molecules. The effects of the multimode vibronic coupling are suggested for the O 1s-12πu and O 1s-13sσg resonances.

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Symmetry-resolved absorption spectra of vibrationally excited CO2 molecules

Abstract

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