Symmetry-resolved absorption spectra of vibrationally excited CO2 molecules

T. Tanaka, C. Makochekanwa, H. Tanaka, M. Kitajima, M. Hoshino, Y. Tamenori, E. Kukk, X. J. Liu, G. Prümper, K. Ueda

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Symmetry-resolved x-ray absorption spectroscopy has been first carried out on high-temperature molecules. From the angle-resolved ion yield spectra of CO2 both at room temperature and at 430°C, symmetry-resolved absorption profiles of the C 1s-12πu and O 1s-12πu resonances have been extracted for the vibrational ground state molecules and bending-vibration excited ones. The profiles change dramatically between them, and the Renner-Teller effect becomes more evident for the vibrationally excited molecules. The effects of the multimode vibronic coupling are suggested for the O 1s-12πu and O 1s-13sσg resonances.

Original languageEnglish
Article number203002
JournalPhysical review letters
Volume95
Issue number20
DOIs
Publication statusPublished - 2005 Nov 11

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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