Symmetries and dissociation dynamics of F 1s core excited states of BF3

Y. Shimizu, Kiyoshi Ueda, H. Chiba, Misaki Okunishi, K. Ohmori, J. B. West, Y. Sato, T. Hayaishi

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

Using the photoelectron-energy-selected photoion coincidence technique, we find that photoions of BF3 with kinetic energy larger than 4 eV are predominantly F+ in the F 1s ionization region whereas B+ is more intense than F+ at the F 1s→2a2″ excitation. Two partial cross sections σ and σ for A1′→E′ parallel and A1′→A2″ perpendicular transitions are obtained from the angular distribution measurement of energetic photoions and the symmetries of some F 1s core excited states are confirmed. The dissociation dynamics of the F 1s-12a2″ core excited state are discussed in detail.

Original languageEnglish
Pages (from-to)2419-2423
Number of pages5
JournalJournal of Chemical Physics
Volume107
Issue number7
DOIs
Publication statusPublished - 1997 Aug 15

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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