Switching of Electron and Ion Conductions by Reversible H2O Sorption in n-Type Organic Semiconductors

Haruka Abe, Ayumi Kawasaki, Takashi Takeda, Norihisa Hoshino, Wakana Matsuda, Shu Seki, Tomoyuki Akutagawa

    Research output: Contribution to journalArticlepeer-review

    6 Citations (Scopus)

    Abstract

    Polar H2O molecules generally act as trapping sites and suppress the electron mobility of n-Type organic semiconductors, making chemical design of H2O-Tolerant and responsive n-Type semiconductors an important step toward multifunctional electron-ion coupling devices. The introduction of effective electrostatic interactions between potassium ions (K+) and carboxylate (-COO-) anions into the electron-Transporting naphthalenediimide I-framework enables the design of high-performance H2O-Tolerant n-Type semiconductors with a reversible H2O adsorption-desorption ability, where the electron mobility and K+ ionic conductivity were coupled with the reversible H2O sorption behavior. The reversible H2O adsorption into the crystals enhanced the electron mobility from 0.04 to 0.28 cm2 V-1 s-1, whereas the K+ ionic conductivity decreased from 3.4 × 10-5 to 4.7 × 10-7 S cm-1. Because this reversible electron-ion conducting switch is responsive to H2O sorption behavior, it is a strong candidate for H2O gating carrier transport systems.

    Original languageEnglish
    Pages (from-to)37391-37399
    Number of pages9
    JournalACS Applied Materials and Interfaces
    Volume12
    Issue number33
    DOIs
    Publication statusPublished - 2020 Aug 19

    Keywords

    • HO adsorption
    • dielectric response
    • electron transport
    • ionic conductor
    • naphthalenediimide
    • organic salt
    • organic semiconductor

    ASJC Scopus subject areas

    • Materials Science(all)

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