Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-: P -quinodimethanide radicals

Ryuta Ishikawa, Shunya Ueno, Hiroaki Iguchi, Brian K. Breedlove, Masahiro Yamashita, Satoshi Kawata

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The reaction of a doubly bis(2-pyridyl)pyrazolate (bpypz-) bridged dinuclear cationic copper(ii) complex with 7,7′,8,8′-tetracyano-p-quinodimethanido radicals (TCNQ-) afforded a tetranuclear complex, [Cu4(μ-bpypz)4(μ-TCNQ)2](TCNQ)2 (1), which self-assembles into a three-dimensional supramolecular coordination architecture via complementary weak coordination bonding and π-π stacking interactions.

Original languageEnglish
Pages (from-to)159-163
Number of pages5
JournalCrystEngComm
Volume22
Issue number2
DOIs
Publication statusPublished - 2019

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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