Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) 2]- salt

Daisuke Sato; Tomoyuki Akutagawa; Sadamu Takeda; Shin Ichiro Noro; Takayoshi Nakamura

doi:10.1021/ic061831u

Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) ₂]^- salt

Daisuke Sato, Tomoyuki Akutagawa, Sadamu Takeda, Shin Ichiro Noro, Takayoshi Nakamura

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Adamantylammonium (ADNH₃⁺) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH₃ ⁺)([18]crown6), which was introduced into a [Ni(dmit) ₂]^- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)₂]^- layers in the crystal, in which the molecular rotation of (ADNH₃ ⁺)([18]-crown-6) was confirmed from the temperature-dependent solid-state ¹H NMR.

Original language	English
Pages (from-to)	363-365
Number of pages	3
Journal	Inorganic chemistry
Volume	46
Issue number	2
DOIs	https://doi.org/10.1021/ic061831u
Publication status	Published - 2007 Jan 22
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) 2]- salt",

abstract = "Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3 +)([18]crown6), which was introduced into a [Ni(dmit) 2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3 +)([18]-crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.",

author = "Daisuke Sato and Tomoyuki Akutagawa and Sadamu Takeda and Noro, {Shin Ichiro} and Takayoshi Nakamura",

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AU - Sato, Daisuke

AU - Akutagawa, Tomoyuki

AU - Takeda, Sadamu

AU - Noro, Shin Ichiro

AU - Nakamura, Takayoshi

PY - 2007/1/22

Y1 - 2007/1/22

N2 - Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3 +)([18]crown6), which was introduced into a [Ni(dmit) 2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3 +)([18]-crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.

AB - Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3 +)([18]crown6), which was introduced into a [Ni(dmit) 2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3 +)([18]-crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.

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Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) ₂]^- salt

Abstract

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