Abstract
Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3 +)([18]crown6), which was introduced into a [Ni(dmit) 2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3 +)([18]-crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.
Original language | English |
---|---|
Pages (from-to) | 363-365 |
Number of pages | 3 |
Journal | Inorganic chemistry |
Volume | 46 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2007 Jan 22 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry