Supramolecular enantiodifferentiating photoisomerization of cyclooctene with modified β-cyclodextrins: Critical control by a host structure

Runhua Lu; Cheng Yang; Yujuan Cao; Zhizhong Wang; Takehiko Wada; Wei Jiao; Tadashi Mori; Yoshihisa Inoue

doi:10.1039/b714300a

Supramolecular enantiodifferentiating photoisomerization of cyclooctene with modified β-cyclodextrins: Critical control by a host structure

Runhua Lu, Cheng Yang, Yujuan Cao, Zhizhong Wang, Takehiko Wada, Wei Jiao, Tadashi Mori, Yoshihisa Inoue

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Enantiodifferentiating photoisomerization of (Z)-cyclooctene included and sensitized by m-methoxybenzoyl-β-cyclodextrin gave chiral (E)-isomers in up to 46% enantiomeric excess, which is the highest value ever reported for supramolecular photochirogenesis with analogous hosts, thus demonstrating the crucial role of the sensitizer-spacer moiety in supramolecular photochirogenic systems.

Original language	English
Pages (from-to)	374-376
Number of pages	3
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/b714300a
Publication status	Published - 2008 Jan 11
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b714300a

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Supramolecular enantiodifferentiating photoisomerization of cyclooctene with modified β-cyclodextrins : Critical control by a host structure. / Lu, Runhua; Yang, Cheng; Cao, Yujuan; Wang, Zhizhong; Wada, Takehiko; Jiao, Wei; Mori, Tadashi; Inoue, Yoshihisa.

In: Chemical Communications, No. 3, 11.01.2008, p. 374-376.

Research output: Contribution to journal › Article › peer-review

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