Supramolecular architectonics with carbon nanoclusters

Jian Yu Zheng, Kentaro Tashiro, Yusuke Hirabayashi, Kazushi Kinbara, Kazuhiko Saigo, Takuzo Aida, Shigeru Sakamoto, Kentaro Yamaguchi

Research output: Contribution to journalArticlepeer-review

152 Citations (Scopus)

Abstract

Supramolecular interaction of fullerenes with cyclic dimers metalloporphyrins (1-m, M = central metal ions) showed a pronounced dependence on the nature of the metal ions, whereby 1-RhMe/fullerene systems displayed extremely high association constants (ca. 108M-1) and low dissociaton activities. Crystal-structure analysis and NMR data suggested a charge-transfer interaction and van der Waals interactions between the host and guest.

Original languageEnglish
Pages (from-to)1857-1861
Number of pages5
JournalAngewandte Chemie - International Edition
Volume40
Issue number10
DOIs
Publication statusPublished - 2001 May 18

Keywords

  • Fullerenes
  • Inclusion compunds
  • Pi interactions
  • Porphyrinoids
  • Rhodium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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