2D- and 1H-NMR in α-(h8-ET)2ND4Hg(SCN)4 and α-(d8-ET)2NH4Hg(SCN)4

S. Endo, T. Goto, T. Fukase, H. Uozaki, K. Okamoto, M. Yamaguchi, N. Toyota

Research output: Contribution to journalConference articlepeer-review

Abstract

We have measured the temperature dependence of the spectrum and the spin-lattice relaxation time T1 by 2D nuclear-magnetic-resonance (NMR) for α-(h8-ET)2ND4Hg(SCN)4 and 1H-NMR for α-(d8-ET)2NH4Hg(SCN)4 in order to clarify the molecular dynamics of the non-centrosymmetric ND4+ and NH4+ ions. Both the systems show the peak in T1-1 around 40 K explained by Bloembergen-Purcell-Pound model, while the temperature dependence of the spectra were quite different.

Original languageEnglish
Pages (from-to)2073-2074
Number of pages2
JournalSynthetic Metals
Volume103
Issue number1-3
DOIs
Publication statusPublished - 1999 Jun 24
EventProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
Duration: 1998 Jul 121998 Jul 18

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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