14N ENDOR study on bis(2-hydroxylphenyl ketoxime)-63Cu(II) complex

Yuan Zhi Xu, De Yu Chen, Chao Rong Cheng, Miyamoto Ryo, Ohba Yasunori, Iwaizumi Masamoto, Cheng Ming Zhou, Yao Huan Chen

Research output: Contribution to journalArticlepeer-review

Abstract

The ENDOR spectrum of 14N-63Cu-HAP complex in DMSO EtOH (5:1) freezing solution at 20 K has been studied using orientational selective method in this paper. The anisotropic superhyperfine coupling tensor and quadrupole coupling tensor of ligand 14N nucleus, and the superhyperfine coupling tensor of various 1H nuclei have been measured precisely. Comparing the superhyperfine coupling tensor of 14N-nucleus with previous work shows that the analytical method of spectrum is reasonable and the data are reliable in our previous work.

Original languageEnglish
Pages (from-to)1052-1060
Number of pages9
JournalScience in China (Scientia Sinica) Series B
Volume36
Issue number9
Publication statusPublished - 1993 Sep
Externally publishedYes

Keywords

  • Cu complex
  • ENDOR
  • ESR
  • N
  • bis(2-hydroxylphenyl ketoxime)

ASJC Scopus subject areas

  • Environmental Science(all)
  • Engineering(all)
  • Earth and Planetary Sciences(all)

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