- salt with flexible supramolecular cation rotator

Qiong Ye, Ping Ping Shi, Zi Qi Chen, Tomoyuki Akutagawa, Shin Ichiro Noro, Takayoshi Nakamura

    Research output: Contribution to journalArticlepeer-review

    Abstract

    [Ni(dmit) 2] - salt (dmit 2 - 2-thioxo-1,3-dithiole-4,5-dithiolate) with flexible supramolecular cation (4-cyanomethylanilinium)(dibenzo[18]crown-6) has been synthesized and investigated its structure, magnetism and rotation. The comparable large steric hindrances limit the rotation of cyanomethyl group to result in no phase transition occurred. Magnetic and potential energy calculations by DFT method were consistent with the magnetic and structure measurements.

    Original languageEnglish
    Pages (from-to)219-224
    Number of pages6
    JournalInorganic Chemistry Communications
    Volume20
    DOIs
    Publication statusPublished - 2012 Jun

    Keywords

    • Crystal engineering
    • Flexible
    • Molecular rotator
    • Supramolecule

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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