Studies toward the total synthesis of nakiterpiosin: construction of the CDE ring system by a transannular Diels-Alder strategy

Tomonori Ito, Masahiro Ito, Hirokazu Arimoto, Hiroyoshi Takamura, Daisuke Uemura

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The transannular Diels-Alder (TADA) reaction was applied to the synthesis of the CDE ring system of nakiterpiosin (1). Tetracyclic compound 25 may be a key intermediate in the total synthesis of 1.

Original languageEnglish
Pages (from-to)5465-5469
Number of pages5
JournalTetrahedron Letters
Volume48
Issue number31
DOIs
Publication statusPublished - 2007 Jul 30

Keywords

  • Nakiterpiosin
  • Synthetic study
  • Transannular Diels-Alder reaction

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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