Studies aimed at the total synthesis of azadirachtin. A modeled connection of C-8 and C-14 in azadirachtin

Takehiro Fukuzaki, Satoshi Kobayashi, Takamasa Hibi, Yohei Ikuma, Jun Ishihara, Naoki Kanoh, Akio Murai

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)

Abstract

(figure presented) Studies on the connection between the right and left segments of azadirachtin are described. The Ireland-Claisen rearrangement of Li-enolate of the modeled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield. †Current address: 6-14-4 Asabu-cho, Kita-ku, Sapporo 001-0045, Japan.

Original languageEnglish
Pages (from-to)2877-2880
Number of pages4
JournalOrganic letters
Volume4
Issue number17
DOIs
Publication statusPublished - 2002 Aug 22

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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