Structures and physical properties of BEDT-TTF salts containing channels of protons

Akane Akutsu-Sato, Hiroki Akutsu, Scott S. Turner, Delphine Le Pevelen, Peter Day, Mark E. Light, Michael B. Hursthouse, Tomoyuki Akutagawa, Takayoshi Nakamura

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Charge transfer salts with stoichiometry β″-(BEDT-TTF) 4[M(C2O4),](18-crown-6 ether)(9HxO), where M= Cr, Ga or Fe and x= 2 or 3 are reported. Their structures suggest that proton migration is possible. Variable temperature resistivity measurements on the Cr salt show metallic behaviour down to 180K. Magnetic susceptibility of the Cr salt is paramagnetic down to 1.8 K. Preliminary impedance measurements suggest that the proton conductivities of the Cr and Ga salts are the order of 10-3 S cm-1 at 300 K.

Original languageEnglish
Pages (from-to)597-598
Number of pages2
JournalSynthetic Metals
Volume135-136
DOIs
Publication statusPublished - 2003 Apr 4
Externally publishedYes

Keywords

  • Organic conductors based on radical cation salts

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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