Structures and magnetic properties of metal cubes

Masayuki Nihei, Norihisa Hoshino, Tasuku Ito, Hiroki Oshio

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Structures and magnetic properties of copper(II), nickel(II) and manganese(II) cubes are presented. In the cubes, four metal ions are assembled into the cubes by tridentate Schiff base ligands. Magnetic succeptibility measurements revealed the copper and nickel cubes have high-spin ground state, while the manganese cube has a S = 0 spin ground state.

Original languageEnglish
Pages (from-to)2359-2362
Number of pages4
JournalPolyhedron
Volume22
Issue number14-17
DOIs
Publication statusPublished - 2003 Jul 15

Keywords

  • Copper
  • Cubane structure
  • Magnetic measurement
  • Manganese
  • Nickel
  • Shiff base

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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