Structures and magnetic properties of metal cubes

Masayuki Nihei; Norihisa Hoshino; Tasuku Ito; Hiroki Oshio

doi:10.1016/S0277-5387(03)00159-1

Structures and magnetic properties of metal cubes

Masayuki Nihei, Norihisa Hoshino, Tasuku Ito, Hiroki Oshio

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Structures and magnetic properties of copper(II), nickel(II) and manganese(II) cubes are presented. In the cubes, four metal ions are assembled into the cubes by tridentate Schiff base ligands. Magnetic succeptibility measurements revealed the copper and nickel cubes have high-spin ground state, while the manganese cube has a S = 0 spin ground state.

Original language	English
Pages (from-to)	2359-2362
Number of pages	4
Journal	Polyhedron
Volume	22
Issue number	14-17
DOIs	https://doi.org/10.1016/S0277-5387(03)00159-1
Publication status	Published - 2003 Jul 15
Externally published	Yes

Keywords

Copper
Cubane structure
Magnetic measurement
Manganese
Nickel
Shiff base

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(03)00159-1

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title = "Structures and magnetic properties of metal cubes",

abstract = "Structures and magnetic properties of copper(II), nickel(II) and manganese(II) cubes are presented. In the cubes, four metal ions are assembled into the cubes by tridentate Schiff base ligands. Magnetic succeptibility measurements revealed the copper and nickel cubes have high-spin ground state, while the manganese cube has a S = 0 spin ground state.",

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author = "Masayuki Nihei and Norihisa Hoshino and Tasuku Ito and Hiroki Oshio",

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T1 - Structures and magnetic properties of metal cubes

AU - Nihei, Masayuki

AU - Hoshino, Norihisa

AU - Ito, Tasuku

AU - Oshio, Hiroki

PY - 2003/7/15

Y1 - 2003/7/15

N2 - Structures and magnetic properties of copper(II), nickel(II) and manganese(II) cubes are presented. In the cubes, four metal ions are assembled into the cubes by tridentate Schiff base ligands. Magnetic succeptibility measurements revealed the copper and nickel cubes have high-spin ground state, while the manganese cube has a S = 0 spin ground state.

AB - Structures and magnetic properties of copper(II), nickel(II) and manganese(II) cubes are presented. In the cubes, four metal ions are assembled into the cubes by tridentate Schiff base ligands. Magnetic succeptibility measurements revealed the copper and nickel cubes have high-spin ground state, while the manganese cube has a S = 0 spin ground state.

KW - Copper

KW - Cubane structure

KW - Magnetic measurement

KW - Manganese

KW - Nickel

KW - Shiff base

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U2 - 10.1016/S0277-5387(03)00159-1

DO - 10.1016/S0277-5387(03)00159-1

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JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 14-17

ER -

Structures and magnetic properties of metal cubes

Abstract

Keywords

ASJC Scopus subject areas

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