Structures and magnetic properties of di and tetranuclear nickel(II) complexes with schiff base ligands

Norihisa Hoshino; Tasuku Ito; Masayuki Nihei; Hiroki Oshio

doi:10.1246/cl.2002.844

Structures and magnetic properties of di and tetranuclear nickel(II) complexes with schiff base ligands

Norihisa Hoshino, Tasuku Ito, Masayuki Nihei, Hiroki Oshio

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Reactions of Ni(CH₃COO)₂·4H₂O and NiCl₂·6H₂O with Schiff base ligands yielded di and tetranuclear nickel(II) complexes of [Ni₂(Hhsae)₂(CH₃COO)₂(MeOH) ₂] (1) and [Ni₄(sae)₄(MeOH)₄] (2) (H₂sae = 2-(5-hydroxysalicylideneamino)ethanol and H₂sae = 2-salicylideneaminoethanol). Magnetic susceptibility measurements revealed that 1 and 2 have singlet and nonet spin ground states, respectively.

Original language	English
Pages (from-to)	844-845
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.2002.844
Publication status	Published - 2002 Aug 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Structures and magnetic properties of di and tetranuclear nickel(II) complexes with schiff base ligands",

abstract = "Reactions of Ni(CH3COO)2·4H2O and NiCl2·6H2O with Schiff base ligands yielded di and tetranuclear nickel(II) complexes of [Ni2(Hhsae)2(CH3COO)2(MeOH) 2] (1) and [Ni4(sae)4(MeOH)4] (2) (H2sae = 2-(5-hydroxysalicylideneamino)ethanol and H2sae = 2-salicylideneaminoethanol). Magnetic susceptibility measurements revealed that 1 and 2 have singlet and nonet spin ground states, respectively.",

author = "Norihisa Hoshino and Tasuku Ito and Masayuki Nihei and Hiroki Oshio",

year = "2002",

month = aug,

day = "5",

doi = "10.1246/cl.2002.844",

language = "English",

pages = "844--845",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "8",

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TY - JOUR

T1 - Structures and magnetic properties of di and tetranuclear nickel(II) complexes with schiff base ligands

AU - Hoshino, Norihisa

AU - Ito, Tasuku

AU - Nihei, Masayuki

AU - Oshio, Hiroki

PY - 2002/8/5

Y1 - 2002/8/5

N2 - Reactions of Ni(CH3COO)2·4H2O and NiCl2·6H2O with Schiff base ligands yielded di and tetranuclear nickel(II) complexes of [Ni2(Hhsae)2(CH3COO)2(MeOH) 2] (1) and [Ni4(sae)4(MeOH)4] (2) (H2sae = 2-(5-hydroxysalicylideneamino)ethanol and H2sae = 2-salicylideneaminoethanol). Magnetic susceptibility measurements revealed that 1 and 2 have singlet and nonet spin ground states, respectively.

AB - Reactions of Ni(CH3COO)2·4H2O and NiCl2·6H2O with Schiff base ligands yielded di and tetranuclear nickel(II) complexes of [Ni2(Hhsae)2(CH3COO)2(MeOH) 2] (1) and [Ni4(sae)4(MeOH)4] (2) (H2sae = 2-(5-hydroxysalicylideneamino)ethanol and H2sae = 2-salicylideneaminoethanol). Magnetic susceptibility measurements revealed that 1 and 2 have singlet and nonet spin ground states, respectively.

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DO - 10.1246/cl.2002.844

M3 - Article

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SP - 844

EP - 845

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 8

ER -

Structures and magnetic properties of di and tetranuclear nickel(II) complexes with schiff base ligands

Abstract

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