Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly

Zhao Yang Li; Jing Wei Dai; Marko Damjanović; Takuya Shiga; Jin Hua Wang; Jia Zhao; Hiroki Oshio; Masahiro Yamashita; Xian He Bu

doi:10.1002/anie.201900789

Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly

Zhao Yang Li, Jing Wei Dai, Marko Damjanović, Takuya Shiga, Jin Hua Wang, Jia Zhao, Hiroki Oshio, Masahiro Yamashita, Xian He Bu

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

We report three self-assembled iron complexes that comprised an anti-parallel open form (o-L _anti ), a parallel open form (o-L _syn ), and a closed form (c-L) of diarylethene conformers. Under kinetic control, Fe ^II ₂ (o-L _anti ) ₃ was isolated, which exhibited a dinuclear structure with diamagnetic properties. Under light-irradiation control, Fe ^II ₂ (c-L) ₃ was prepared and exhibited paramagnetism and spin-crossover behaviour. Under thermodynamic control and in the presence of indispensable [Fe ^III (Tp*)(CN) ₃ ] ⁻ , Fe ^II ₂ (o-L _anti ) ₃ and Fe ^II ₂ (c-L) ₃ transformed into tetranuclear Fe ^III ₂ Fe ^II ₂ (o-L _syn ) ₂ , which exhibited complete spin-crossover behaviour at T _1/2 =353 K.

Original language	English
Pages (from-to)	4339-4344
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	13
DOIs	https://doi.org/10.1002/anie.201900789
Publication status	Published - 2019 Mar 22

Keywords

iron complexes
photochromism
self-assembly
spin-crossover
supramolecular chemistry

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201900789

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Li, Z. Y., Dai, J. W., Damjanović, M., Shiga, T., Wang, J. H., Zhao, J., Oshio, H., Yamashita, M., & Bu, X. H. (2019). Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly. Angewandte Chemie - International Edition, 58(13), 4339-4344. https://doi.org/10.1002/anie.201900789

Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly. / Li, Zhao Yang; Dai, Jing Wei; Damjanović, Marko; Shiga, Takuya; Wang, Jin Hua; Zhao, Jia; Oshio, Hiroki; Yamashita, Masahiro; Bu, Xian He.

In: Angewandte Chemie - International Edition, Vol. 58, No. 13, 22.03.2019, p. 4339-4344.

Research output: Contribution to journal › Article › peer-review

Li, ZY, Dai, JW, Damjanović, M, Shiga, T, Wang, JH, Zhao, J, Oshio, H, Yamashita, M & Bu, XH 2019, 'Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly', Angewandte Chemie - International Edition, vol. 58, no. 13, pp. 4339-4344. https://doi.org/10.1002/anie.201900789

Li, Zhao Yang ; Dai, Jing Wei ; Damjanović, Marko ; Shiga, Takuya ; Wang, Jin Hua ; Zhao, Jia ; Oshio, Hiroki ; Yamashita, Masahiro ; Bu, Xian He. / Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly. In: Angewandte Chemie - International Edition. 2019 ; Vol. 58, No. 13. pp. 4339-4344.

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title = "Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly",

abstract = " We report three self-assembled iron complexes that comprised an anti-parallel open form (o-L anti ), a parallel open form (o-L syn ), and a closed form (c-L) of diarylethene conformers. Under kinetic control, Fe II 2 (o-L anti ) 3 was isolated, which exhibited a dinuclear structure with diamagnetic properties. Under light-irradiation control, Fe II 2 (c-L) 3 was prepared and exhibited paramagnetism and spin-crossover behaviour. Under thermodynamic control and in the presence of indispensable [Fe III (Tp*)(CN) 3 ] − , Fe II 2 (o-L anti ) 3 and Fe II 2 (c-L) 3 transformed into tetranuclear Fe III 2 Fe II 2 (o-L syn ) 2 , which exhibited complete spin-crossover behaviour at T 1/2 =353 K. ",

keywords = "iron complexes, photochromism, self-assembly, spin-crossover, supramolecular chemistry",

author = "Li, {Zhao Yang} and Dai, {Jing Wei} and Marko Damjanovi{\'c} and Takuya Shiga and Wang, {Jin Hua} and Jia Zhao and Hiroki Oshio and Masahiro Yamashita and Bu, {Xian He}",

note = "Funding Information: Z.Y.L. thanks Nankai University for the start-up fund for young talent researchers. This work was supported by the National Natural Science Foundation of China (NSFC, 21701088 and 21531005) and National Science Foundation of Tianjin City (17JCYBJC41000). Z.Y.L. would like to thank Professor Yasutaka Kitagawa at Osaka University for the DFT calculations.",

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AU - Shiga, Takuya

AU - Wang, Jin Hua

AU - Zhao, Jia

AU - Oshio, Hiroki

AU - Yamashita, Masahiro

AU - Bu, Xian He

N1 - Funding Information: Z.Y.L. thanks Nankai University for the start-up fund for young talent researchers. This work was supported by the National Natural Science Foundation of China (NSFC, 21701088 and 21531005) and National Science Foundation of Tianjin City (17JCYBJC41000). Z.Y.L. would like to thank Professor Yasutaka Kitagawa at Osaka University for the DFT calculations.

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N2 - We report three self-assembled iron complexes that comprised an anti-parallel open form (o-L anti ), a parallel open form (o-L syn ), and a closed form (c-L) of diarylethene conformers. Under kinetic control, Fe II 2 (o-L anti ) 3 was isolated, which exhibited a dinuclear structure with diamagnetic properties. Under light-irradiation control, Fe II 2 (c-L) 3 was prepared and exhibited paramagnetism and spin-crossover behaviour. Under thermodynamic control and in the presence of indispensable [Fe III (Tp*)(CN) 3 ] − , Fe II 2 (o-L anti ) 3 and Fe II 2 (c-L) 3 transformed into tetranuclear Fe III 2 Fe II 2 (o-L syn ) 2 , which exhibited complete spin-crossover behaviour at T 1/2 =353 K.

AB - We report three self-assembled iron complexes that comprised an anti-parallel open form (o-L anti ), a parallel open form (o-L syn ), and a closed form (c-L) of diarylethene conformers. Under kinetic control, Fe II 2 (o-L anti ) 3 was isolated, which exhibited a dinuclear structure with diamagnetic properties. Under light-irradiation control, Fe II 2 (c-L) 3 was prepared and exhibited paramagnetism and spin-crossover behaviour. Under thermodynamic control and in the presence of indispensable [Fe III (Tp*)(CN) 3 ] − , Fe II 2 (o-L anti ) 3 and Fe II 2 (c-L) 3 transformed into tetranuclear Fe III 2 Fe II 2 (o-L syn ) 2 , which exhibited complete spin-crossover behaviour at T 1/2 =353 K.

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