Structure sensitivity of double inner-shell holes in sulfur-containing molecules

P. Linusson, O. Takahashi, K. Ueda, J. H.D. Eland, R. Feifel

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

To demonstrate the structure sensitivity of double inner-shell hole spectroscopy, we have measured energies of H2S2+, SO 22+, and CS22+ with the two vacancies in the sulfur 2p shell using a multielectron coincidence technique combined with synchrotron radiation. We describe how to extract intrinsic chemical information which is masked by the orbital relaxation effect in conventional core-level photoelectron spectroscopy.

Original languageEnglish
Article number022506
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume83
Issue number2
DOIs
Publication statusPublished - 2011 Feb 18

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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