To demonstrate the structure sensitivity of double inner-shell hole spectroscopy, we have measured energies of H2S2+, SO 22+, and CS22+ with the two vacancies in the sulfur 2p shell using a multielectron coincidence technique combined with synchrotron radiation. We describe how to extract intrinsic chemical information which is masked by the orbital relaxation effect in conventional core-level photoelectron spectroscopy.
|Journal||Physical Review A - Atomic, Molecular, and Optical Physics|
|Publication status||Published - 2011 Feb 18|
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics