Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column

Kazuya Nakata; Yuuko Yoshino; Hatsune Hara; Toshio Manabe; Tomohiko Ishii; Hitoshi Miyasaka; Masahiro Yamashita; Hiroyuki Matsuzaka; Motomi Katada

doi:10.1080/10587250290101441

Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column

Kazuya Nakata, Yuuko Yoshino, Hatsune Hara, Toshio Manabe, Tomohiko Ishii, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaka, Motomi Katada

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

A novel charge transfer complex containing of hexacyanoferrate (Fe(CN) ₆) unit, which has been exhibited variety of magnetic topics in Prussian blue systems, was synthesized. X-ray analysis of the single crystal obtained by electrolysis of BEDT-TTF (ET) and hexacyanoferrate suggests that this complex contains ID magnetic hexacyanoferrate chain perpendicular to the conducting ET column. This significant structure implies that significant properties can be expected caused by the interaction between the spin momentum on d-electrons and a conducting π-electrons influenced vertically by the applied magnetic field. From the result of the electrical conducting measurement, it is suggested that is a semiconductor, with the activation energy and the conductivity at room temperature to be 0.113eV and 0.46S/cm. respectivity. Detailed X-ray analysis suggests that the occupancies of Fe and C elements in the ID hexacyanoferrate chain are 0.5, that of N element is 1.0.

Original language	English
Pages (from-to)	117-122
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	380
DOIs	https://doi.org/10.1080/10587250290101441
Publication status	Published - 2002
Externally published	Yes
Event	Proceedings of the International Chemical Congress of the Pacific Basin Societies (PACIFICHEM 2001): Proceedings of the Symposium on Twenty years of Organic Superconductors: New Materials, New Insights - Honolulu, HI, United States Duration: 2000 Dec 14 → 2000 Dec 19

Keywords

BEDT-TTF
Charge transfer complex; crystal structure
Hexacyanoferrate
Magnetic properties

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/10587250290101441

Cite this

Nakata, K., Yoshino, Y., Hara, H., Manabe, T., Ishii, T., Miyasaka, H., Yamashita, M., Matsuzaka, H., & Katada, M. (2002). Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 380, 117-122. https://doi.org/10.1080/10587250290101441

Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column. / Nakata, Kazuya; Yoshino, Yuuko; Hara, Hatsune et al.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 380, 2002, p. 117-122.

Research output: Contribution to journal › Conference article › peer-review

Nakata, K, Yoshino, Y, Hara, H, Manabe, T, Ishii, T, Miyasaka, H, Yamashita, M, Matsuzaka, H & Katada, M 2002, 'Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 380, pp. 117-122. https://doi.org/10.1080/10587250290101441

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abstract = "A novel charge transfer complex containing of hexacyanoferrate (Fe(CN) 6) unit, which has been exhibited variety of magnetic topics in Prussian blue systems, was synthesized. X-ray analysis of the single crystal obtained by electrolysis of BEDT-TTF (ET) and hexacyanoferrate suggests that this complex contains ID magnetic hexacyanoferrate chain perpendicular to the conducting ET column. This significant structure implies that significant properties can be expected caused by the interaction between the spin momentum on d-electrons and a conducting π-electrons influenced vertically by the applied magnetic field. From the result of the electrical conducting measurement, it is suggested that is a semiconductor, with the activation energy and the conductivity at room temperature to be 0.113eV and 0.46S/cm. respectivity. Detailed X-ray analysis suggests that the occupancies of Fe and C elements in the ID hexacyanoferrate chain are 0.5, that of N element is 1.0.",

keywords = "BEDT-TTF, Charge transfer complex; crystal structure, Hexacyanoferrate, Magnetic properties",

author = "Kazuya Nakata and Yuuko Yoshino and Hatsune Hara and Toshio Manabe and Tomohiko Ishii and Hitoshi Miyasaka and Masahiro Yamashita and Hiroyuki Matsuzaka and Motomi Katada",

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journal = "Molecular Crystals and Liquid Crystals",

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T1 - Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column

AU - Nakata, Kazuya

AU - Yoshino, Yuuko

AU - Hara, Hatsune

AU - Manabe, Toshio

AU - Ishii, Tomohiko

AU - Miyasaka, Hitoshi

AU - Yamashita, Masahiro

AU - Matsuzaka, Hiroyuki

AU - Katada, Motomi

PY - 2002

Y1 - 2002

N2 - A novel charge transfer complex containing of hexacyanoferrate (Fe(CN) 6) unit, which has been exhibited variety of magnetic topics in Prussian blue systems, was synthesized. X-ray analysis of the single crystal obtained by electrolysis of BEDT-TTF (ET) and hexacyanoferrate suggests that this complex contains ID magnetic hexacyanoferrate chain perpendicular to the conducting ET column. This significant structure implies that significant properties can be expected caused by the interaction between the spin momentum on d-electrons and a conducting π-electrons influenced vertically by the applied magnetic field. From the result of the electrical conducting measurement, it is suggested that is a semiconductor, with the activation energy and the conductivity at room temperature to be 0.113eV and 0.46S/cm. respectivity. Detailed X-ray analysis suggests that the occupancies of Fe and C elements in the ID hexacyanoferrate chain are 0.5, that of N element is 1.0.

AB - A novel charge transfer complex containing of hexacyanoferrate (Fe(CN) 6) unit, which has been exhibited variety of magnetic topics in Prussian blue systems, was synthesized. X-ray analysis of the single crystal obtained by electrolysis of BEDT-TTF (ET) and hexacyanoferrate suggests that this complex contains ID magnetic hexacyanoferrate chain perpendicular to the conducting ET column. This significant structure implies that significant properties can be expected caused by the interaction between the spin momentum on d-electrons and a conducting π-electrons influenced vertically by the applied magnetic field. From the result of the electrical conducting measurement, it is suggested that is a semiconductor, with the activation energy and the conductivity at room temperature to be 0.113eV and 0.46S/cm. respectivity. Detailed X-ray analysis suggests that the occupancies of Fe and C elements in the ID hexacyanoferrate chain are 0.5, that of N element is 1.0.

KW - BEDT-TTF

KW - Charge transfer complex; crystal structure

KW - Hexacyanoferrate

KW - Magnetic properties

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ER -

Structure, magnetic and electronic properties of charge transfer complex containing hexacyanoferrate chain and BEDT-TTF column

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