Structure and stability of water soluble (NH4)8[Ti4(C6H4O 7)4(O2)4]·8H2O

M. Kakihana, M. Tada, M. Shiro, V. Petrykin, M. Osada, Y. Nakamura

Research output: Contribution to journalArticlepeer-review

149 Citations (Scopus)


Ammonium citratoperoxotitanate(IV), (NH4)8[Ti4(C6H4O 7)4(O2)4]·8H2O, was isolated in the solid form. Its crystal structure was solved and refined using single-crystal X-ray data. The compound crystallizes in a monoclinic cell With a = 10.237(2).Å, b = 17.537(4) Å, c = 14.713(3) Å, β = 100.35(1)° (Z = 2, fw = 1360.40, ρcalc = 1.74 g/cm3) and space group P21/n (No. 14). The determined structure of the titanium complex agrees well with the Raman and NMR spectroscopic data. We speculate that tight coordination of titanium in the complex molecule is responsible for the high stability of this compound against hydrolysis.

Original languageEnglish
Pages (from-to)891-894
Number of pages4
JournalInorganic chemistry
Issue number5
Publication statusPublished - 2001 Feb 26
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry


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