Structure and reactivity of a novel parallel thiosulfito (SSO2-S:S) rhodium dinuclear complex

Kimie Shiomi, Brian K. Breedlove, Hiroaki Kitayama, Takanori Nishioka, Isamu Kinoshita, Nobuaki Koga, Kiyoshi Isobe

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The parallel thiosulfite ligand (SSO2) in a rhodium complex, which is formed by oxygenation of a bridging disulfide, is converted to a bridging hydrocarbyl thiolate ligand and sulfur dioxide gas by the reaction with hydrocarbyl halides.

Original languageEnglish
Pages (from-to)1756-1757
Number of pages2
JournalChemical Communications
Volume2
Issue number16
DOIs
Publication statusPublished - 2002 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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