Structure and electronic properties of TTF bisannulated 24-crown-8 charge transfer complexes

Y. Abe; T. Akutagawa; T. Hasegawa; T. Nakamura; K. Sugiura; Y. Sakata; T. Inabe; C. A. Christensen; J. Becher

doi:10.1016/S0379-6779(98)00387-7

Structure and electronic properties of TTF bisannulated 24-crown-8 charge transfer complexes

Y. Abe, T. Akutagawa, T. Hasegawa, T. Nakamura, K. Sugiura, Y. Sakata, T. Inabe, C. A. Christensen, J. Becher

Research output: Contribution to journal › Conference article › peer-review

4 Citations (Scopus)

Abstract

Charge transfer (CT) complexes of tetrathiafulvalene bisannulated 24-crown-8 (1) with tetrafluoro (F₄)-, 2,5-dibromo (Br₂)-, 2,5-dichloro (Cl₂)-tetracyanoquinodimethane (TCNQ), and 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) were prepared. The electronic ground state of the acceptor varies from the completely ionic to partial charge transfer state. Within the CT complexes the donor 1 was completely oxidized to the divalent cationic state 1²⁺. The molecular conformation of 1²⁺ in Cl₂-TCNQ complex was an intra-dimer form folded over the flexible part of macrocyclic 24-crown-8.

Original language	English
Pages (from-to)	1599-1600
Number of pages	2
Journal	Synthetic Metals
Volume	102
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00387-7
Publication status	Published - 1999
Externally published	Yes
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: 1998 Jul 12 → 1998 Jul 18

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(98)00387-7

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@article{4a415fe538df4fd38ace43519bdacc02,

title = "Structure and electronic properties of TTF bisannulated 24-crown-8 charge transfer complexes",

abstract = "Charge transfer (CT) complexes of tetrathiafulvalene bisannulated 24-crown-8 (1) with tetrafluoro (F4)-, 2,5-dibromo (Br2)-, 2,5-dichloro (Cl2)-tetracyanoquinodimethane (TCNQ), and 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) were prepared. The electronic ground state of the acceptor varies from the completely ionic to partial charge transfer state. Within the CT complexes the donor 1 was completely oxidized to the divalent cationic state 12+. The molecular conformation of 12+ in Cl2-TCNQ complex was an intra-dimer form folded over the flexible part of macrocyclic 24-crown-8.",

author = "Y. Abe and T. Akutagawa and T. Hasegawa and T. Nakamura and K. Sugiura and Y. Sakata and T. Inabe and Christensen, {C. A.} and J. Becher",

year = "1999",

doi = "10.1016/S0379-6779(98)00387-7",

language = "English",

volume = "102",

pages = "1599--1600",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

note = "Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) ; Conference date: 12-07-1998 Through 18-07-1998",

}

TY - JOUR

T1 - Structure and electronic properties of TTF bisannulated 24-crown-8 charge transfer complexes

AU - Abe, Y.

AU - Akutagawa, T.

AU - Hasegawa, T.

AU - Nakamura, T.

AU - Sugiura, K.

AU - Sakata, Y.

AU - Inabe, T.

AU - Christensen, C. A.

AU - Becher, J.

PY - 1999

Y1 - 1999

N2 - Charge transfer (CT) complexes of tetrathiafulvalene bisannulated 24-crown-8 (1) with tetrafluoro (F4)-, 2,5-dibromo (Br2)-, 2,5-dichloro (Cl2)-tetracyanoquinodimethane (TCNQ), and 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) were prepared. The electronic ground state of the acceptor varies from the completely ionic to partial charge transfer state. Within the CT complexes the donor 1 was completely oxidized to the divalent cationic state 12+. The molecular conformation of 12+ in Cl2-TCNQ complex was an intra-dimer form folded over the flexible part of macrocyclic 24-crown-8.

AB - Charge transfer (CT) complexes of tetrathiafulvalene bisannulated 24-crown-8 (1) with tetrafluoro (F4)-, 2,5-dibromo (Br2)-, 2,5-dichloro (Cl2)-tetracyanoquinodimethane (TCNQ), and 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) were prepared. The electronic ground state of the acceptor varies from the completely ionic to partial charge transfer state. Within the CT complexes the donor 1 was completely oxidized to the divalent cationic state 12+. The molecular conformation of 12+ in Cl2-TCNQ complex was an intra-dimer form folded over the flexible part of macrocyclic 24-crown-8.

UR - http://www.scopus.com/inward/record.url?scp=0033137655&partnerID=8YFLogxK

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U2 - 10.1016/S0379-6779(98)00387-7

DO - 10.1016/S0379-6779(98)00387-7

M3 - Conference article

AN - SCOPUS:0033137655

VL - 102

SP - 1599

EP - 1600

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1-3

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

Y2 - 12 July 1998 through 18 July 1998

ER -

Structure and electronic properties of TTF bisannulated 24-crown-8 charge transfer complexes

Abstract

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