Abstract
The electronic structures of quasi-one-dimensional halogen-bridged mixed-metal compounds [Ni1-xPdx(chxn)2Br] Br2 were investigated by means of powder X-ray diffraction measurements. Unit cell lengths of all directions obeyed a linear relationship when x < 0.9, whereas those deviated when x > 0.9 especially in the case of the b and c axes. This deviation can be explained by a phase change from an MIII Mott-Hubbard state to an MII-MIV charge-density-wave state because of chemical pressure caused by the substitution of Pd ions into [Pd(chxn)2Br]Br2 with smaller Ni ions.
| Original language | English |
|---|---|
| Pages (from-to) | 3694-3696 |
| Number of pages | 3 |
| Journal | Inorganic chemistry |
| Volume | 49 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2010 Apr 19 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Fingerprint Dive into the research topics of 'Structural study of electronic states in quasi-one-dimensional halogen-bridged mixed-metal complexes [Ni<sub>1-x</sub>Pd<sub>x</sub>(chxn) <sub>2</sub>Br]Br<sub>2</sub>'. Together they form a unique fingerprint.
Cite this
Takaishi, S., Wu, H., Xie, J., Kajiwara, T., Breedlove, B. K., Miyasaka, H., & Yamashita, M. (2010). Structural study of electronic states in quasi-one-dimensional halogen-bridged mixed-metal complexes [Ni1-xPdx(chxn) 2Br]Br2. Inorganic chemistry, 49(8), 3694-3696. https://doi.org/10.1021/ic1001368