Structural Domain Switching by Magnetic Fields in RAl₃C₃ (R = Rare Earth)

Hexagonal-to-orthorhombic structural transitions in RAl₃C₃ have been studied by X-ray diffraction for R = Yb, Tm, Er, Dy, and Lu. We report how orthorhombic domains are controlled by adjusting external magnetic fields. It is shown that orthorhombic domains in RAl₃C₃ can be aligned by the field when the R ion is magnetic. It is also shown that a single-domain state can be switched to another single-domain state by the field even in paramagnetic states with small induced moments. For R = Lu, however, it was not possible to change the multidomain state by a field of up to 70 kOe. We discuss that domain selection and switching are caused by magnetic anisotropies in the orthorhombic phase of RAl₃C₃. We also propose an idea to explain the field-induced antiferromagnetism revealed by Khalyavin et al.