Structural change in SrSiO3 induced by introduction of nitrogen

Makoto Kobayashi, Jihae Kim, Hironori Sato, Takuya Yasunaga, Hideki Kato, Kotaro Fujii, Masahiro Shiraiwa, Masatomo Yashima, Masato Kakihana

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

SrSiO3 1 3xN2x with a single chain inosilicate structure, which has not been realized in Sr and Sr-rich metasilicates, has been synthesized by introduction of a small amount of nitrogen into SrSiO3. Its crystal structure was determined by a single-crystal X-ray analysis. Anion sites are severely distorted along b-axis, resulting in formation of the inosilicate structure. The present material activated with Eu2+ exhibits red emission under near ultraviolet and visible light irradiation. Our results suggest a new strategy for development of novel oxynitrides.

Original languageEnglish
Pages (from-to)1327-1329
Number of pages3
JournalChemistry Letters
Volume47
Issue number10
DOIs
Publication statusPublished - 2018 Jan 1

Keywords

  • New compound
  • Oxynitride
  • Phosphor

ASJC Scopus subject areas

  • Chemistry(all)

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