Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S 4] to [(η5-C5Me5) 2Fe2S4](PF6)2

Hiroshi Ogino, Hiromi Tobita, Shinji Inomata, Mamoru Shimoi

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Electrochemical oxidation of [(η5-C5Me 5)2Fe2S4] in MeCN containing NH 4PF6 affords [(η5-C5Me 5)2Fe2S4](PF6) 2 in which a bidentate μ-S2 ligand in the parent complex is converted to a doubly bidentate μ-S2 ligand; the structure of the resulting Fe2S4 core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.

Original languageEnglish
Pages (from-to)586-587
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
Publication statusPublished - 1988 Jan 1

ASJC Scopus subject areas

  • Molecular Medicine

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