Structural and Li-ion diffusion properties of lithium tantalum phosphate LiTa2PO8

Norikazu Ishigaki, Kunimitsu Kataoka, Daisuke Morikawa, Masami Terauchi, Kikuko Hayamizu, Junji Akimoto

    Research output: Contribution to journalArticlepeer-review

    6 Citations (Scopus)

    Abstract

    We synthesized a polycrystalline LiTa2PO8 sample at 1323 K by a solid-state reaction. The crystal structure of LiTa2PO8 was examined by selected-area electron diffraction (SAED) and convergent-beam electron diffraction (CBED) techniques. Electrochemical impedance measurements showed that the total conductivity at room temperature was 4.85 × 10−4 S cm−1 and the activation energy was 0.52 eV. The high Li-ion conductive properties were confirmed by 7Li pulse-field gradient (PFG) or pulse-gradient spin-echo (PGSE) NMR spectroscopy. The activation energy of the Li diffusion (0.51 eV) measured by PFG NMR was well consistent with the result of impedance measurement. We believe that the LiTa2PO8 would be as one of the important candidates for the solid electrolyte used in all solid-state lithium batteries.

    Original languageEnglish
    Article number115314
    JournalSolid State Ionics
    Volume351
    DOIs
    Publication statusPublished - 2020 Aug

    Keywords

    • Convergent beam electron diffraction
    • Li PFG NMR
    • Lithium ion battery (LIB)
    • Lithium tantalum phosphate
    • Solid electrolyte

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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