Strategy for Finely Aligned Gold Nanorod Arrays Using Polymer Brushes as a Template

Satoshi Nakamura, Hideyuki Mitomo, Yu Sekizawa, Takeshi Higuchi, Yasutaka Matsuo, Hiroshi Jinnai, Kuniharu Ijiro

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The development of a strategy for the assembly of nanoscale building blocks, in particular, anisotropic nanoparticles, into desired structures is important for the construction of functional materials and devices. However, control over the orientation of rod-shaped nanoparticles on a substrate for integration into solid-state devices remains challenging. Here, we report a strategy for the fabrication of finely aligned gold nanorod (GNR) arrays using polymer (DNA) brushes as a nanoscale template. The gold nanorods modified with cationic surface ligands were electrostatically adsorbed onto the DNA brush substrates under various conditions. The orientational behavior of the GNRs was examined by spectral analyses and transmission electron microtomography (TEMT). As a result, we found several important factors, such as moderate interaction between GNRs and polymers and polymer densities on the substrate, related to the vertical alignment of GNRs on the substrates. We also developed a purification method to remove the undesired adsorption of GNRs onto the arrays. Finally, we have succeeded in the fabrication of extensive vertical GNR arrays of high quality via the easy bottom-up process.

Original languageEnglish
Pages (from-to)3590-3599
Number of pages10
JournalLangmuir
Volume36
Issue number13
DOIs
Publication statusPublished - 2020 Apr 7

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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