Stereospecific synthesis of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole using aryl diphenylphosphinite and azide compounds by a new type of oxidation-reduction condensation

Kiichi Kuroda; Yuji Maruyama; Yujiro Hayashi; Teruaki Mukaiyama

doi:10.1246/cl.2008.836

Stereospecific synthesis of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole using aryl diphenylphosphinite and azide compounds by a new type of oxidation-reduction condensation

Kiichi Kuroda, Yuji Maruyama, Yujiro Hayashi, Teruaki Mukaiyama

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The preparation of alkyl aryl Sulfides from alcohols and 2-sulfanylbenzothiazole using phenyl diphenylphosphinite and azide compounds by a new type of oxidation-reduction condensation is described. The chiral secondary and tertiary alcohols are converted into the corresponding chiral Sulfides with almost complete inversion of configurations under mild and neutral conditions.

Original language	English
Pages (from-to)	836-837
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	8
DOIs	https://doi.org/10.1246/cl.2008.836
Publication status	Published - 2008 Aug 5
Externally published	Yes

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Chemistry(all)

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10.1246/cl.2008.836

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Stereospecific synthesis of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole using aryl diphenylphosphinite and azide compounds by a new type of oxidation-reduction condensation. / Kuroda, Kiichi; Maruyama, Yuji; Hayashi, Yujiro; Mukaiyama, Teruaki.

In: Chemistry Letters, Vol. 37, No. 8, 05.08.2008, p. 836-837.

Research output: Contribution to journal › Article › peer-review

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AU - Hayashi, Yujiro

AU - Mukaiyama, Teruaki

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AB - The preparation of alkyl aryl Sulfides from alcohols and 2-sulfanylbenzothiazole using phenyl diphenylphosphinite and azide compounds by a new type of oxidation-reduction condensation is described. The chiral secondary and tertiary alcohols are converted into the corresponding chiral Sulfides with almost complete inversion of configurations under mild and neutral conditions.

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Stereospecific synthesis of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole using aryl diphenylphosphinite and azide compounds by a new type of oxidation-reduction condensation

Abstract

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