Stereoselective synthesis of a KLM ring model of ciguatoxin: Confirmation of the C54 stereochemistry

Makoto Sasaki, Atsuhiro Hasegawa, Kazuo Tachibana

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)

Abstract

A ciguatoxin KLM ring model and its C54 epimer were stereoselectively synthesized. Comparison of their 1H NMR data with that on the natural toxin established the earlier stereochemical assignment at the C54 position.

Original languageEnglish
Pages (from-to)8489-8492
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number52
DOIs
Publication statusPublished - 1993
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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