Abstract
A highly stereoselective synthesis of the racemic oxatetracyclic core of platensimycin has been accomplished from a known bicyclic epoxy lactone by an 11-step sequence that involves a Diels-Alder cyclcoaddition to construct its cis-decalenone structural motif with complete regio- and stereoselectivity and a ring-closing metathesis to establish its whole carbon framework.
Original language | English |
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Pages (from-to) | 2798-2801 |
Number of pages | 4 |
Journal | Journal of Organic Chemistry |
Volume | 78 |
Issue number | 6 |
DOIs | |
Publication status | Published - 2013 Mar 15 |
ASJC Scopus subject areas
- Organic Chemistry