Abstract
A highly stereoselective synthesis of the racemic oxatetracyclic core of platensimycin has been accomplished from a known bicyclic epoxy lactone by an 11-step sequence that involves a Diels-Alder cyclcoaddition to construct its cis-decalenone structural motif with complete regio- and stereoselectivity and a ring-closing metathesis to establish its whole carbon framework.
| Original language | English |
|---|---|
| Pages (from-to) | 2798-2801 |
| Number of pages | 4 |
| Journal | Journal of Organic Chemistry |
| Volume | 78 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2013 Mar 15 |
ASJC Scopus subject areas
- Organic Chemistry
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Horii, S., Torihata, M., Nagasawa, T., & Kuwahara, S. (2013). Stereoselective approach to the racemic oxatetracyclic core of platensimycin. Journal of Organic Chemistry, 78(6), 2798-2801. https://doi.org/10.1021/jo302813y