Stereoselective approach to the racemic oxatetracyclic core of platensimycin

Sakuya Horii, Munefumi Torihata, Tomohiro Nagasawa, Shigefumi Kuwahara

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A highly stereoselective synthesis of the racemic oxatetracyclic core of platensimycin has been accomplished from a known bicyclic epoxy lactone by an 11-step sequence that involves a Diels-Alder cyclcoaddition to construct its cis-decalenone structural motif with complete regio- and stereoselectivity and a ring-closing metathesis to establish its whole carbon framework.

Original languageEnglish
Pages (from-to)2798-2801
Number of pages4
JournalJournal of Organic Chemistry
Volume78
Issue number6
DOIs
Publication statusPublished - 2013 Mar 15

ASJC Scopus subject areas

  • Organic Chemistry

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