Abstract
A tricyclic compound possessing oxabicyclo[2.2.1]heptane and seven-membered ring of solanoeclepin A, the most active hatching agent of potato cyst nematode, was synthesized from d-pantolactone. The synthesis features a tin-mediated 6-exo-trig radical cyclization followed by iodoetherification and ring-closing enyne metathesis.
Original language | English |
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Article number | 658 |
Pages (from-to) | 965-969 |
Number of pages | 5 |
Journal | Synlett |
Volume | 26 |
Issue number | 7 |
DOIs | |
Publication status | Published - 2015 Apr 1 |
Externally published | Yes |
Keywords
- enyne metathesis
- iodoetherification
- natural products
- radical cyclization
- solanoeclepin A
ASJC Scopus subject areas
- Organic Chemistry