Stereochemistry of vinylogous rubottom oxidation of proline-fused cyclohexadienol silyl ether

Kentaro Okano, Shun Okaya, Taichi Kurogi, Hideto Fujiwara, Hidetoshi Tokuyama

Research output: Contribution to journalArticlepeer-review

Abstract

The steric effect of vinylogous Rubottom oxidation of proline-fused cyclohexadienol silyl ether was investigated. The facial selectivity in the oxidation is governed by a synergistic effect of the proximal ester and a protective group on the nitrogen.

Original languageEnglish
Pages (from-to)1299-1308
Number of pages10
JournalHeterocycles
Volume90
Issue number2
DOIs
Publication statusPublished - 2015

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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