Steam Gasification of Low-Rank Coal with a Nanoscale Ca/Na Composite Catalyst Prepared by Ion Exchange

Naoto Tsubouchi, Yuuki Mochizuki, Yuji Shinohara, Yuu Hanaoka, Takemitsu Kikuchi, Yasuo Ohtsuka

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Ca2+ and Na+ cations were separately or consecutively ion-exchanged with an Indonesian low-rank coal using saturated aqueous solutions of Ca(OH)2 and/or soda ash at 20-40 °C without pH adjustment. This was done by adding aqueous solutions of the soda ash and/or calcium hydroxide to a dispersion of coal particles in deionized water, while monitoring the Na+ and Ca2+ concentrations and pH of the resulting mixture. A 3.5 mass % Ca2+-exchanged coal, a 1.6 mass % Na+-exchanged coal and a 3.8 mass % Ca2+- and 1.0 mass % Na+-exchanged coal were obtained. The catalytic pyrolysis and subsequent gasification of these ion-exchanged specimens were performed in a fixed bed quartz reactor at 650, 700, or 750 °C. X-ray diffraction analyses of the samples pyrolyzed at 700 °C found no evidence of Na or Ca species, indicating that these were present as nanoscale particles. The Ca2+/Na+-exchanged coal underwent steam gasification more readily than the other samples, with complete char conversion of this material following 1 h of processing at 700 °C. The use of a binary metal catalyst was also found to lower the required reaction temperature by more than 100 °C.

Original languageEnglish
Pages (from-to)226-232
Number of pages7
JournalEnergy and Fuels
Volume32
Issue number1
DOIs
Publication statusPublished - 2018 Jan 18

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology

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    Tsubouchi, N., Mochizuki, Y., Shinohara, Y., Hanaoka, Y., Kikuchi, T., & Ohtsuka, Y. (2018). Steam Gasification of Low-Rank Coal with a Nanoscale Ca/Na Composite Catalyst Prepared by Ion Exchange. Energy and Fuels, 32(1), 226-232. https://doi.org/10.1021/acs.energyfuels.7b02964