Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts

Minkee Choi, Kyungsu Na, Jeongnam Kim, Yasuhiro Sakamoto, Osamu Terasaki, Ryong Ryoo

Research output: Contribution to journalArticlepeer-review

1464 Citations (Scopus)

Abstract

Zeolitesmicroporous crystalline aluminosilicatesare widely used in petrochemistry and fine-chemical synthesis because strong acid sites within their uniform micropores enable size- and shape-selective catalysis. But the very presence of the micropores, with aperture diameters below 1 nm, often goes hand-in-hand with diffusion limitations that adversely affect catalytic activity. The problem can be overcome by reducing the thickness of the zeolite crystals, which reduces diffusion path lengths and thus improves molecular diffusion. This has been realized by synthesizing zeolite nanocrystals, by exfoliating layered zeolites, and by introducing mesopores in the microporous material through templating strategies or demetallation processes. But except for the exfoliation, none of these strategies has produced ultrathin zeolites with thicknesses below 5 nm. Here we show that appropriately designed bifunctional surfactants can direct the formation of zeolite structures on the mesoporous and microporous length scales simultaneously and thus yield MFI (ZSM-5, one of the most important catalysts in the petrochemical industry) zeolite nanosheets that are only 2 nm thick, which corresponds to the b-axis dimension of a single MFI unit cell. The large number of acid sites on the external surface of these zeolites renders them highly active for the catalytic conversion of large organic molecules, and the reduced crystal thickness facilitates diffusion and thereby dramatically suppresses catalyst deactivation through coke deposition during methanol-to-gasoline conversion. We expect that our synthesis approach could be applied to other zeolites to improve their performance in a range of important catalytic applications.

Original languageEnglish
Pages (from-to)246-249
Number of pages4
JournalNature
Volume461
Issue number7261
DOIs
Publication statusPublished - 2009 Sep 10

ASJC Scopus subject areas

  • General

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