Stable Silylenes and Their Transition Metal Complexes

Takeaki Iwamoto; Shintaro Ishida

doi:10.1016/B978-0-12-801981-8.00008-3

Stable Silylenes and Their Transition Metal Complexes

Takeaki Iwamoto, Shintaro Ishida

SCI - Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

14 Citations (Scopus)

Abstract

Recent dramatic progress in the chemistry of stable (persistent and isolable) silylenes (divalent silicon species) reported since the year 2000 are summarized. Stable silylenes with the various substituents and the various coordination numbers around the divalent silicon atom have been available, which make their chemistry one of the most exciting and important research areas in silicon chemistry. In this chapter, the recent progress in the synthesis, molecular structure studies, and reactivity of stable silylenes including ligation for transition metal complexes are described.

Original language	English
Title of host publication	Organosilicon Compounds
Subtitle of host publication	Theory and Experiment (Synthesis)
Publisher	Elsevier Inc.
Pages	361-532
Number of pages	172
ISBN (Electronic)	9780128019917
ISBN (Print)	9780128019818
DOIs	https://doi.org/10.1016/B978-0-12-801981-8.00008-3
Publication status	Published - 2017 Aug 21

Keywords

Isolable
Molecular structure
Persistent
Silylene
Synthesis
Transition metal complex

ASJC Scopus subject areas

Chemistry(all)

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10.1016/B978-0-12-801981-8.00008-3

Cite this

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AU - Ishida, Shintaro

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N2 - Recent dramatic progress in the chemistry of stable (persistent and isolable) silylenes (divalent silicon species) reported since the year 2000 are summarized. Stable silylenes with the various substituents and the various coordination numbers around the divalent silicon atom have been available, which make their chemistry one of the most exciting and important research areas in silicon chemistry. In this chapter, the recent progress in the synthesis, molecular structure studies, and reactivity of stable silylenes including ligation for transition metal complexes are described.

AB - Recent dramatic progress in the chemistry of stable (persistent and isolable) silylenes (divalent silicon species) reported since the year 2000 are summarized. Stable silylenes with the various substituents and the various coordination numbers around the divalent silicon atom have been available, which make their chemistry one of the most exciting and important research areas in silicon chemistry. In this chapter, the recent progress in the synthesis, molecular structure studies, and reactivity of stable silylenes including ligation for transition metal complexes are described.

KW - Isolable

KW - Molecular structure

KW - Persistent

KW - Silylene

KW - Synthesis

KW - Transition metal complex

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M3 - Chapter

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BT - Organosilicon Compounds

PB - Elsevier Inc.

ER -

Stable Silylenes and Their Transition Metal Complexes

Abstract

Keywords

ASJC Scopus subject areas

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